Results 121 to 130 of about 643,193 (264)

Infrared Irradiation‐Assisted Pd‐Catalyzed C(sp3)─H Arylation and Tandem Cyclization of Ortho‐Tolualdehydes

Chemistry – A European Journal, EarlyView.
A rapid and efficient protocol for the synthesis of 2‐benzylbenzaldehydes and anthracenes is reported, based on the infrared (IR) irradiation‐assisted Pd‐catalyzed C(sp3)─H arylation and the tandem C(sp3)─H arylation/electrophilic aromatic cyclization of ortho‐tolualdehydes with aryl iodides via a transient directing group (TGD) strategy.
Matteo Renato Martina, Ambra Maria Fiore, Angela Punzi, Gianluigi Albano, Roberta Ragni, Pietro Cotugno, Gianluca Maria Farinola   +6 more
wiley   +1 more source

Catalytic asymmetric [4 + 2] dearomative photocycloadditions of anthracene and its derivatives with alkenylazaarenes

Nature Communications
Photocatalysis through energy transfer has been investigated for the facilitation of [4 + 2] cycloaddition reactions. However, the high reactivity of radical species poses a challenging obstacle to achieving enantiocontrol with chiral catalysts, as no ...
Dong Tian, Wenshuo Shi, Xin Sun, Xiaowei Zhao, Yanli Yin, Zhiyong Jiang   +5 more
doaj   +1 more source

Illuminating Olympicenes: Insights Into Anti‐Kasha Photophysics in Polycyclic Aromatic Hydrocarbons

Chemistry – A European Journal, EarlyView.
Compact olympicene‐based chromophores reveal unexpectedly rich excited‐state behavior, including dual fluorescence, excitation‐dependent emission, and anti‐Kasha‐type emission. Tunable locally excited and intramolecular charge‐transfer states emerge from subtle structural changes, expanding the design rules for polycyclic aromatic chromophores and ...
Wenlong Li, Stephen Awuku, Mia E. Dionne, Jordyn L. Gunderson, Marc R. MacKinnon, Amy L. Stevens   +5 more
wiley   +1 more source

The effect of anthracene derivatives on the state of the extracellular matrix of the periodontal connective tissue and the oral mucosa of old rats

Journal of Education, Health and Sport, 2019
In the experiments on 27 old female rats, the effect of the anthracene derivative preparation on the state of the intercellular matrix of the connective tissue of the periodontal and oral mucosa in intact animals, as well as on the periodontitis model ...
N. N. Savelieva, O. V. Suslova, S. A. Schneider, E. K. Tkachenko   +3 more
doaj  

Synthesis and characterization of 1,2,3,4-naphthalene and anthracene diimides

Beilstein Journal of Organic Chemistry
We report the synthesis and characterization of naphthalene and anthracene scaffolds end-capped by cyclic imides. The solid-state structures of the N-phenyl derivatives, determined by X-ray crystallography, reveal changes in packing preference based on ...
Adam D. Bass, Daniela Castellanos, Xavier A. Calicdan, Dennis D. Cao   +3 more
doaj   +1 more source

Photoreversible Polyurea Actuators With Spatiotemporal Control and Adaptive Mechanics

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A light–thermal responsive polyurea network incorporating reversibly dimerizable anthracene units enables spatiotemporal modulation of cross‐linking density and nearly 400‐fold stiffness tuning. Integrating programmable anisotropy, photopatterning, self‐healing, and photowelding within a single framework, this bioinspired “one network–multifunction ...
Zhiwen Song, Wang Li, Xinru Guo, Rui Pu, Wenxin Wang, Yujun Cheng, Liang Shen, Fei Gao   +7 more
wiley   +1 more source

Gas–Solid Interface‐Assisted Growth of Organic Semiconductor Single Crystals: Dimensions, Structures, Mechanisms, and Applications

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Gas–solid interface‐assisted growth strategies have unlocked precise control over crystal structure, morphology, dimension, and molecular packing. The obtained organic semiconductor single crystals represent the ideal candidates for high‐performance organic optoelectronic devices.
Tingyi Yan, Qing Tian, Jinwen Wang, Ke Jiang, Yage Han, Yuanzhuang Ren, Lingyun Li, Xiujuan Zhang, Jiansheng Jie   +8 more
wiley   +1 more source

Modular π‐Extended IF‐TTF Systems: Tuning Redox and Optical Properties in Donor–Acceptor and Donor–Donor Frameworks

European Journal of Organic Chemistry, EarlyView.
Donor–acceptor and donor–donor systems incorporating an indeno[1,2‐b]fluorene‐extended tetrathiafulvalene (IF‐TTF) donor motif were prepared by Suzuki coupling reactions. The compounds were studied for their optical and redox properties. The compounds showed multiredox behavior with several accessible redox states. A series of π‐extended donor–acceptor
Cecilie Rindom, Mogens Brøndsted Nielsen   +1 more
wiley   +1 more source

Fluorene‐based blue emitters: On the path to electrically pumped organic lasers

FlexMat, EarlyView.
Electrically pumped efficient operation remains unrealized, a major challenge in optoelectronics. Fluorene‐based blue‐emitting semiconductors are promising gain media, thanks to their structural tunability and favorable emission properties. This review summarizes recent advances, highlights their reliability and versatility in lasing, and outlines key ...
Yong Yan, Hao Li, Mengna Yu, Huiyin Wang, Jiangqiang He, Menghan Wu, Quanyou Feng, Linghai Xie   +7 more
wiley   +1 more source

o‐Carborane‐based multi‐resonance thermally activated delayed fluorescence emitter exhibits highly efficient and multifunctional electroluminescence

FlexMat, EarlyView.
By strategically incorporating boron/nitrogen multi‐resonance (B/N‐MR) core into the o‐carborane unit, perfect exciton utilization can be achieved as well as exhibiting stimuli‐responsive properties. The resulting DBN‐oCb‐based organic light‐emitting diode (OLED) demonstrated an impressive external quantum efficiency of 22.3%, the highest reported for ...
Jiasen Zhang, Denghui Liu, Mengke Li, Tong Wang, Yuanyuan Meng, Deli Li, Shi‐Jian Su, Wei Li, Ziyi Ge   +8 more
wiley   +1 more source