Results 121 to 130 of about 5,778 (287)

Addition polymers from 1,4,5,8-tetrahydro-1,4;5,8-diepoxyanthracene and Bis-dienes: Processable resins for high temperature application [PDF]

1,4,5,8-Tetrahydro-1,4;5,8-diepoxyanthracene reacts with various anthracene endcapped polyimide oligomers to form Diels-Alder cycloaddition copolymers.
Meador, Mary Ann B.
core   +1 more source

Charge-Transfer Forces in the Self-Assembly of Heteromolecular Reactive Solids:  Successful Design of Unique (Single-Crystal-to-Single-Crystal) Diels−Alder Cycloadditions [PDF]

, 2001
Electron donor/acceptor (EDA) interactions are found to be a versatile methodology for the engineering of reactive heteromolecular crystals. In this way, a series of the charge-transfer π-complexes between bis(alkylimino)-1,4-dithiin acceptors and ...
Kim, J. H., Kochi, Jay K., Lindeman, Sergey V.   +2 more
core   +1 more source

Methane Pyrolysis Performance in Catalytic Molten Media for Hydrogen Production From the Perspective of Bubble Column Reactor Design and Configuration

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT In the hydrogen production routes from natural gas (methane), methane pyrolysis offers a cleaner option than the established steam methane reforming by producing CO2‐free hydrogen. However, in fixed bed reactors over solid catalysts, this technology experiences rapid catalyst deactivation due to carbon (coke) deposition encapsulating its ...
Muhammad Irfan Fakarudin, Luqmanulhakim Baharudin, Matthew J. Watson, Wan Nor Roslam Wan Isahak   +3 more
wiley   +1 more source

Construction of Lean Coal Molecular Structure Model Based on Spectroscopic Characterization

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT The chemical structure of coal exerts a profound influence on its properties and utilization pathways. A comprehensive analysis of coal's molecular structure is crucial for mitigating environmental pollution arising from coal combustion and improving the efficiency of coal utilization.
Song Liu, Hao Xia, Tao Ge, Yaling Bai, Shoulan Wang, Yunfang Liu   +5 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

5,12‐TIPS‐Substitution of Tetracene: Effects on Redox Potentials and Cyclic Voltammetric Behavior in CH2Cl2 and THF1

Chemistry – A European Journal, EarlyView.
Tetracene and bis(tri(isopropyl)silylethynyl)tetracene (TIPS‐tetracene) exhibit characteristic similarities and differences in their electrochemical redox behavior depending on the base solvent of the electrolyte. Analysis of cyclic voltammograms allows the quantification of substituent and solvent effects and the calculation of an “electrochemical gap.
Holger F. Bettinger, Simon Schundelmeier, Bernd Speiser   +2 more
wiley   +1 more source

Toward Larger Cyclo‐9,10‐Anthryleneparaphenylenes

Chemistry – A European Journal, EarlyView.
During a macrocyclization with a dihydroanthracene diol as corner unit, larger oligomers than the trimer and tetramer were formed and isolated up to the nonamer. Their three‐dimensional structures were studied by X‐ray diffraction. The most abundant macrocycles were rearomatized to the corresponding CPP derivatives.
Moritz P. Schuldt, Frank Rominger, Sven M. Elbert, Michael Mastalerz   +3 more
wiley   +1 more source

The Electronic Spin State of Diradicals Obtained from the Nuclear Perspective: The Strange Case of Chichibabin Radicals

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
The electronic spin state of two Chichibabin radicals is investigated using 2‐dimensional hyperfine correlated Electron Nuclear Double Resonance. The protons (I=1/2) act as a reference for the electronic spin quantum number (S) via their hyperfine interactions.
Gabriel Moise, Saleta Fernández, Kit Joll, Mikhail V. Vaganov, Fátima García, Christiane R. Timmel, Diego Peña, Arzhang Ardavan   +7 more
wiley   +1 more source

Charge State Influence on Stability and Isomerism in Dehydrogenated PAHs: Insights from Anthracene, Acridine, and Phenazine

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
The ionization of anthracene, acridine, and phenazine has been explored, along with the removal of one and two hydrogen atoms, to provide valuable information for astrochemists and to understand the behavior of the resulting structures and their electronic reorganization. Abstract In this study, we systematically explored the stability and isomerism of
Khaldia Zghida, Farouk Hamza Reguig, Manuel Alcamí, Al Mokhtar Lamsabhi   +3 more
wiley   +1 more source

Engineered Metal–Organic Frameworks‐Based Materials for Environmental Detection

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Engineered metal–organic frameworks (MOFs) regulated by various material modification strategies are discussed for environmental contaminant detection under different sensing mechanisms, providing future improvements of MOFs in environmental detection. Sensitive and selective detection of contaminants is crucial for environmental protection.
Pan Gao, Song Wang, Yuechao Yao, Yibo Dou   +3 more
wiley   +1 more source