Results 81 to 90 of about 3,549 (288)

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang   +6 more
wiley   +2 more sources

Ultrastable Self‐Cross‐linkable Electro‐Optic Materials Based on a Bisanthracene Scaffold

open access: yesAdvanced Electronic Materials, EarlyView.
A novel bisanthracene‐based self‐cross‐linkable electro‐optic chromophore (TD2) is developed. TD2 exhibits a high r33 of 141 pm/V and a cross‐linked Tg up to 195 °C, retaining 99.75% of its initial EO response after 500 h at 85 °C, showing record‐high thermal stability for single‐molecule self‐cross‐linking EO materials.
Xingtao Wang   +6 more
wiley   +1 more source

Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals

open access: yesAngewandte Chemie, EarlyView.
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley   +2 more sources

Non-target metabolomics revealed the differences between Rh. tanguticum plants growing under canopy and open habitats

open access: yesBMC Plant Biology, 2021
Background Rheum tanguticum (Rh. tanguticum) is an important traditional Chinese medicine plant, “Dahuang”, which contains productive metabolites and occupies wide habitats on the Qinghai-Tibet plateau.
Feng Xiong   +5 more
doaj   +1 more source

The Chemistry and Biology of Benz[a]anthracenes

open access: yes, 1988
First published in 1988, this volume surveys the chemical synthesis and biological activity of the benz[a]anthracenes. These compounds occur in smoke and mineral oils and a few have been shown to be potent carcinogens. This volume was the first to review,
B. Tierney   +2 more
core   +1 more source

Accelerating Discovery of Organic Molecular Crystals via Materials Informatics and Autonomous Experiments

open access: yesAdvanced Intelligent Discovery, EarlyView.
Materials informatics and autonomous experimentation are transforming the discovery of organic molecular crystals. This review presents an integrated molecule–crystal–function–optimization workflow combining machine learning, crystal structure prediction, and Bayesian optimization with robotic platforms.
Takuya Taniguchi   +2 more
wiley   +1 more source

Aromaticity and conformational deformability of some environmental pollutants - methylated anthracenes

open access: yes, 2014
There is little information on methylated anthracenes which are constituents of diesel fuel. In this paper, a theoretical investigation of some molecular properties of methyl-anthracenes (MAs), 1-MA and 2-MA, and all dimethylanthracene isomers (DMAs), 1 ...
Ostojić, Bojana   +2 more
core  

Therapeutic Applications of Stimuli‐Based Release and Engineering of Extracellular Vesicles

open access: yesAdvanced NanoBiomed Research, EarlyView.
This review summarizes the effects of endogenous and exogenous stimuli, their effects on the natural release of extracellular vesicles, as well as their uptake and release. It also gives an overview of stimuli‐responsive EVs and their therapeutic applications. Extracellular vesicles (EVs), nano‐ to microsized lipid bilayer membrane‐bound particles, are
Gloria Kemunto, Kristen Dellinger
wiley   +1 more source

Color‐Pure Organic Luminophores: Characteristics, Definitions, Physical Basis and Fundamental Design Principles

open access: yesAngewandte Chemie, EarlyView.
Color‐pure all‐organic emitters, i.e., with narrow spectral characteristics, are intensively studied for high‐definition organic LEDs and multi‐color bioimaging. In order to guide targeted materials design, this educative review discusses spectral characteristics, proper definitions and units, and the physical basis of spectral broadening, to distill ...
Johannes Gierschner   +6 more
wiley   +2 more sources

Antibacterial potential and chromatographic profiling of bioactive compounds from endophytic Streptomyces sp. strain MIRK71 isolated from Mirabilis jalapa (L.) [PDF]

open access: yesPeerJ
Multidrug-resistant bacteria pose an alarming global health threat. The persistent rise in antibiotic-resistant infections continues to challenge healthcare systems worldwide.
Lalrokimi   +10 more
doaj   +2 more sources

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