Results 111 to 120 of about 21,191 (233)

Mechanistic deconvolution of BSA size variants by constrained Raman pseudo‐Voigt hard modeling during anion‐exchange chromatography

Biotechnology Progress, EarlyView.
Abstract In biopharmaceutical manufacturing, protein aggregation is a critical quality attribute, necessitating rapid and reliable analytical strategies during downstream processes like anion‐exchange chromatography (AEX). While Raman spectroscopy enables continuous monitoring of protein secondary structure, standard data‐driven regression models ...
Jakob Heyer‐Müller, Robin Schiemer, Lars Robbel, Michael Schmitt, Jürgen Hubbuch   +4 more
wiley   +1 more source

MORPHOANATOMICAL LEAF ANALYSIS IN HORTICULTURAL GROUPS OF AVOCADO (Persea americana) PLACED AT INIA-CENIAP’S COLLECTION, VENEZUELA

Tropical and Subtropical Agroecosystems, 2017
The avocado (Persea americana Mill.) is the most important species of Lauraceae in America due to its exploitation as food for pre-Columbian and modern cultures. It is a very important seasonal crop in Venezuela based on a perennial fruit tree management.
H. Ferrer Pereira, M. B. Raymúndez, I. Pérez-Almeida   +2 more
doaj  

Apical Delta and It's Ramifications: A Literature Review

AbstractThe apical delta represents a complex anatomical configuration at the root apex characterized by multiple accessory and lateral canals that create a branching communication between the pulp space and periapical tissues. Its presence poses significant challenges in endodontic diagnosis, debridement, disinfection, and obturation ...
openaire   +1 more source

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

Chemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel, Shrouq Mujahed, Kamal Uddin Ansari, Katarzyna Młodzikowska‐Pieńko, Renana Gershoni‐Poranne, Yuri Tulchinsky   +5 more
wiley   +1 more source

Routes to Cyclobutadiene and Cycloallyl Pt(II) Complexes: Dicationic Bis(Alkyne) Species as Intermediates

Chemistry – A European Journal, EarlyView.
This work demonstrates the synthesis of cationic Pt(II) η3‐cycloallyl complexes, and experimental and computational studies show a ligand bite‐angle dependence of their formation rates. The reactivity of these complexes with Brønsted acids was investigated, leading to the formation of cationic and dicationic Pt(II) η4‐cyclobutadiene complexes ...
Ouchan He, Froze Jameel, Y. Einar H. Stampehl, Liza M. Richter, Matteo Tosi, Martin Kaupp, Thomas Braun   +6 more
wiley   +1 more source

Tetradecanuclear {Ni9Ln5} Clusters Featuring Encapsulated {Ln5} Trigonal Bipyramids: Modular 3d‐4f Architectures With Broad‐Range Magnetocaloric Response

Chemistry – A European Journal, EarlyView.
The use of 2‐aminoisobutyric acid in 3d–4f chemistry affords three {Ni₉Ln5} clusters, with the Gd analogue exhibiting an unusually broad magnetocaloric effect across an extended temperature range. ABSTRACT The solvothermal reaction between Ni(HCOO)2.2H2O, 2‐aminoisobutyric acid (aibH), Ln(OAc)3·4H2O (Ln = Gd, Y, Dy) and NEt3 in MeOH/MeCN affords the ...
Thomais G. Tziotzi, Evangelia G. Asmargiannaki, Ben Thamm, Scott J. Dalgarno, Emmanouil K. Charkiolakis, Marc Ubach I. Cervera, David Gracia, Marco Evangelisti, Constantinos J. Milios   +8 more
wiley   +1 more source

Analysis of Bond Strength of Bioceramic Sealer Following Irrigation with Chlorhexidine. [PDF]

Iran Endod J
Costa LG, Saldanha JM, da Silva-Filho JE, Aguiar BA, de Almeida Gomes F, Gurgel-Filho ED.   +5 more
europepmc   +1 more source

Bis(2‐Adamantyl)Magnesium: Synthesis, Structure, and Applications of a Versatile and Shelf‐Stable 2‐Adamantyl Anion Equivalent

Chemistry – A European Journal, EarlyView.
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta, Fioralba Taullaj, Jack H. Lin, Ulrich Fekl   +3 more
wiley   +1 more source

On the Design of a Class of Analog Filters Whose Impulse Response Is a Mittag‐Leffler Function

International Journal of Circuit Theory and Applications, EarlyView.
Fractional‐order filters whose impulse response is a Mittag‐Leffler (M‐L) function in any of its known forms are summarized in this work. Simulation results using Cadence and experimental results using an FPAA validate the introduced concept. ABSTRACT Fractional‐order filters whose impulse response is a Mittag‐Leffler (M‐L) function in any of its known
Julia Nako, Costas Psychalinos, Ahmed S. Elwakil, Brent J. Maundy   +3 more
wiley   +1 more source

3D epithelial cell topology tunes signaling range to promote precise patterning. [PDF]

Proc Natl Acad Sci U S A
Paci G, Berkemeier F, Baum B, Page KM, Mao Y.   +4 more
europepmc   +1 more source