Effects of chloride ions in acid-catalyzed biomass dehydration reactions in polar aprotic solvents [PDF]
Nature Communications, 2019 Despite the potential advantages of using polar aprotic solvents for biomass upgrading reactions, fundamental understanding of these solvation effects is limited at present.
Max A. Mellmer +11 more
doaj +5 more sources
Proton solvation in protic and aprotic solvents
Journal of Computational Chemistry, 2016 Protonation pattern strongly affects the properties of molecular systems. To determine protonation equilibria, proton solvation free energy, which is a central quantity in solution chemistry, needs to be known. In this study, proton affinities (PAs), electrostatic energies of solvation, and pKA values were computed in protic and aprotic solvents.
Emanuele Rossini, E. Knapp
semanticscholar +5 more sources
Polymer Chemistry Applications of Cyrene and its Derivative Cygnet 0.0 as Safer Replacements for Polar Aprotic Solvents. [PDF]
ChemSusChem, 2021 This study explores a binary solvent system composed of biobased Cyrene and its derivative Cygnet 0.0 for application in membrane technology and in biocatalytic synthesis of polyesters.
Milescu RA +8 more
europepmc +2 more sources
CO2 Electroreduction in Organic Aprotic Solvents: A Mini Review
Journal of Chemistry, 2022 An annual increase of CO2 concentrations in the atmosphere causes global environmental problems, addressed by systematic research to develop effective technologies for capturing and utilizing carbon dioxide.
Оrest Kuntyi +2 more
doaj +2 more sources
Effects of solvent and structure on the reactivity of 2-substituted nicotinic acids with diazodiphenylmethane in aprotic solvents [PDF]
Journal of the Serbian Chemical Society, 2012 The rate constants for the reactions of diazodiphenylmethane (DDM) with 2-substituted nicotinic acids in nine aprotic solvents at 30°C were determined. The obtained second order rate constants in aprotic solvents, were correlated using the Kamlet-Taft
Drmanić Saša Ž. +2 more
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Study on synthesis of ursodeoxycholic acid by reduction of 7-ketolithocholic acid in double aprotic solvents and molecular simulations [PDF]
Bioresources and Bioprocessing, 2023 Ursodeoxycholic acid (UDCA) is not only safer than chenodeoxycholic acid in the treatment of hepatobiliary diseases, but also has a wide range of applications in Acute Kidney Injury and Parkinson’s Disease.
Mohan Dai +4 more
doaj +2 more sources
Spectrophotometric determination of the acidity constants of calcon in water and mixed water-organic solvents [PDF]
Journal of the Serbian Chemical Society, 2009 The acid-base properties of calcon (1-(2-hydroxy-1-naphthylazo)-2- -naphthol-4-sulfonic acid) in water and mixed water-organic solvents at 25 °C at an ionic strength of 0.10 M are studied by a multiwavelength spectrophotometric method.
Mazloum-Ardakani Mohammad +4 more
doaj +5 more sources
A carbohydrate-anion recognition system in aprotic solvents. [PDF]
Chem Asian J, 2014 AbstractA carbohydrate–anion recognition system in nonpolar solvents is reported, in which complexes form at the B‐faces of β‐D‐pyranosides with H1‐, H3‐, and H5‐cis patterns similar to carbohydrate–π interactions. The complexation effect was evaluated for a range of carbohydrate structures; it resulted in either 1:1 carbohydrate–anion complexes, or 1 ...
Ren B, Dong H, Ramström O.
europepmc +4 more sources
Insights into impact of polar protic and aprotic solvents on bioactive features of 3-(Dimethylaminomethyl)-5-nitroindole: A DFT study and molecular dynamics simulations. [PDF]
PLoS ONEPolar protic and aprotic solvents can effectively simulate the maturation of breast carcinoma cells. Herein, the influence of polar protic solvents (water and ethanol) and aprotic solvents (acetone and DMSO) on the properties of 3-(dimethylaminomethyl)-5-
Stève-Jonathan Koyambo-Konzapa +7 more
doaj +2 more sources
Compensation of London Dispersion in the Gas Phase and in Aprotic Solvents.
Angewandte Chemie - International Edition, 2019 The importance of London dispersion for structure and stability of molecules with less than about 200 atoms has been established in recent years but the quantitative understanding is still largely based on computations because of a persistent lack of ...
R. Pollice +3 more
semanticscholar +3 more sources