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The phosphate cathodes for aqueous zinc-ion batteries
Inorganic Chemistry Frontiers, 2022We categorize phosphate-based cathodes in zinc-ion battery and highlight the relationship between structural properties and energy storage mechanisms. The major problems faced by each kind of materials and rational optimization strategies are summarized.
Xi Li +5 more
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Towards More Sustainable Aqueous Zinc‐Ion Batteries
Angewandte Chemie International EditionAbstract Aqueous zinc‐ion batteries (AZIBs) are considered as the promising candidates for large‐scale energy storage because of their high safety, low cost and environmental benignity. The large‐scale applications of AZIBs will inevitably result in a large amount of spent AZIBs, which not only induce the waste of resources, but also ...
Jiacai Zhu +3 more
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An Aqueous Zinc‐Ion Battery Based on Copper Hexacyanoferrate
ChemSusChem, 2014AbstractA new zinc‐ion battery based on copper hexacyanoferrate and zinc foil in a 20 mM solution of zinc sulfate, which is a nontoxic and noncorrosive electrolyte, at pH 6 is reported. The voltage of this novel battery system is as high as 1.73 V. The system shows cyclability, rate capability, and specific energy values near to those of lithium‐ion ...
Rafael, Trócoli, Fabio, La Mantia
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Separator designs for aqueous zinc-ion batteries
Science BulletinAqueous zinc-ion batteries (AZIBs) are attracting worldwide attention due to their multiple merits such as extreme safety, low cost, feasible assembly, and environmentally friendly enabled by water-based electrolytes. At present, AZIBs have experienced systematic advances in battery components including cathode, anode, and electrolyte, whereas research
Bin, Li +6 more
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“Soggy‐Sand” Chemistry for High‐Voltage Aqueous Zinc‐Ion Batteries
Advanced Materials, 2023AbstractThe narrow electrochemical stability window, deleterious side reactions, and zinc dendrites prevent the use of aqueous zinc‐ion batteries. Here, aqueous “soggy‐sand” electrolytes (synergistic electrolyte‐insulator dispersions) are developed for achieving high‐voltage Zn‐ion batteries.
Rongyu Deng +7 more
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Cathode materials for aqueous zinc-ion batteries: A mini review
Journal of Colloid and Interface Science, 2022Although lithium-ion batteries (LIBs) have many advantages, they cannot satisfy the demands of numerous large energy storage industries owing to their high cost, low security, and low resource richness. Aqueous zinc-ion batteries (ZIBs) with low cost, high safety, and high synergistic efficiency have attracted an increasing amount of attention and are ...
Tao, Zhou +7 more
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Biomimetic Superstructured Interphase for Aqueous Zinc-Ion Batteries
Journal of the American Chemical SocietyThe practical application of aqueous zinc-ion batteries (AZIBs) is greatly challenged by rampant dendrites and pestilent side reactions resulting from an unstable Zn-electrolyte interphase. Herein, we report the construction of a reliable superstructured solid electrolyte interphase for stable Zn anodes by using mesoporous polydopamine (2D-mPDA ...
Yan Ai +13 more
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Tuning Proton Insertion Chemistry for Sustainable Aqueous Zinc‐Ion Batteries
Small, 2023AbstractRechargeable aqueous zinc‐ion batteries (ZIBs) have emerged as an alternative to lithium‐ion batteries due to their affordability and high level of safety. However, their commercialization is hindered by the low mass loading and irreversible structural changes of the cathode materials during cycling.
Gyutae Nam +10 more
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MnO2 superstructure cathode with boosted zinc ion intercalation for aqueous zinc ion batteries
Journal of Colloid and Interface ScienceThe simultaneous intercalation of protons and Zn$^{2+}$ ions in aqueous electrolytes presents a significant obstacle to the widespread adoption of aqueous zinc ion batteries (AZIBs) for large-scale use, a challenge that has yet to be overcome. To address this, we have developed a MnO$_2$/tetramethylammonium (TMA) superstructure with an enlarged ...
Aina Zhang +8 more
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Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries
Angewandte Chemie, 2019AbstractRechargeable aqueous zinc‐ion batteries (ZIBs) are promising energy‐storage devices owing to their low cost and high safety. However, their energy‐storage mechanisms are complex and not well established. Recent energy‐storage mechanisms of ZIBs usually depend on cationic redox processes.
Fang Wan +7 more
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