Results 181 to 190 of about 538,570 (408)

Anthraquinones as Photoredox Catalysts for the Reductive Activation of Aryl Halides

open access: yes, 2018
Quinones are ubiquitous in nature, as structural motif of natural products or redox mediator in biological electron transfer processes. While their oxidation properties have already been widely used in chemical and photochemical reactions, applications ...
J. Bardagi   +4 more
semanticscholar   +1 more source

Recent Developments in Radical Mediated Synthesis of Organostannanes.

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract The present review aims to provide an overview of the recent developments in the preparation of aryl‐ or alkenyl stannanes via carbon‐ and tin‐centered radicals enabling chemists to synthesize organostannyl derivatives with high efficiency and under mild conditions.
Qianhang Ren   +4 more
wiley   +1 more source

Fire-resistant phosphorus containing polyimides and copolyimides [PDF]

open access: yes, 1985
Phosphorus-containing polyimides and copolyimides are synthesized in a two-step polycondensation reaction from 1- (diorganooxyphosphonl)methly 2,4- and 2,6-diaminobenzenes and tetracarboxylic anhydride. The diorgano position of the diorganooxyphosphonyl
Mikroyannidis, J. A.
core   +1 more source

Synthesis of Polysubstituted Naphthalenes via Metal‐Free Borylative Cyclization of o‐Alkynylstyrenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A selective, metal‐free method for the synthesis of boron‐functionalized polysubstituted naphthalenes via BCl3‐mediated cyclization of α‐substituted o‐alkynylstyrenes is described. The reaction exhibits broad substrate scope, tolerating various groups such as ethers, sulfides and halogens, and delivers high yields under mild conditions, even ...
Marcos Humanes   +2 more
wiley   +1 more source

Holographic Gaussian Boson Sampling with Matrix Product States on 3D cQED Processors [PDF]

open access: yes
We introduce quantum circuits for simulations of multi-mode state-vectors on 3D cQED processors, using matrix product state representations. The circuits are demonstrated as applied to simulations of molecular docking based on holographic Gaussian boson sampling, as illustrated for binding of a thiol-containing aryl sulfonamide ligand to the tumor ...
arxiv   +1 more source

Development of Photo‐Biocatalytic Redox System for Asymmetric Synthesis of Optically Active Amines Using Blue Light and Transaminases. A Case Study Toward Mavacamten

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract α‐Chiral amines are versatile building blocks for the asymmetric synthesis of optically pure high‐added‐value chemicals, including pharmaceuticals, agrochemicals, and natural products. Herein, we report a one‐pot, two‐step sequential deracemization of racemic sec‐alcohols to optically enriched primary amines throught a photo‐biocatalytic ...
Natalia Antos   +5 more
wiley   +1 more source

Development of Hydrofluoroolefin (HFO)‐Based Direct O‐Fluoroalkenylation of Phenols Targeting Tyrosine Conjugation

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Methodology for direct fluoroalkenylation of phenolic OH function was developed using a fluorinated electrophilic reagent derived from HFO1234ze gas. Besides various functionalized phenols, tyrosine and tyrosine‐based peptides were successfully conjugated under the optimized reaction conditions.
Rihárd Sisa   +2 more
wiley   +1 more source

Reactivity of acyclic (pentadienyl)iron(1+) cations: Synthetic studies directed toward the frondosins [PDF]

open access: yes, 2011
A short, 4-step route to the scaffold of frondosin A and B is reported. The [1-methoxycarbonyl-5-(2′,5′-dimethoxyphenyl)pentadienyl]Fe(CO)3+ cation was prepared in two steps from (methyl 6-oxo-2,4-hexadienoate)Fe(CO)3.
Lee, Do W   +3 more
core   +1 more source

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