Results 181 to 190 of about 330,962 (287)

Tandem Reactivity of Metal−Carbon and Carbon−Silicon Bonds in Mononuclear α‐Silyl Organolithium or Organosodium Complexes Towards CO, CO2 and Heteroallenes

Angewandte Chemie, EarlyView.
Anionic α‐silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a series of reactions between mononuclear organo‐lithium and ‐sodium complexes with CO, CO2, or heteroallenes.
Xiao Yang, Jack M. Hemingway, Wataru Kanna, Nathan Davison, Hiroki Hayashi, Louise Male, Paul G. Waddell, James A. Dawson, Erli Lu   +8 more
wiley   +2 more sources

Conformationally locked 7-aryl tetrahydroisoquinolines as dual acetylcholinesterase inhibitors and antioxidants: role of intramolecular hydrogen bonding and aryl electronics. [PDF]

Front Pharmacol
Ríos V, Linares-Pipón C, Maulén C, Castro-Álvarez A, Bradshaw B, Romero-Parra J, Cuellar MA, Martínez-Cifuentes M, Parra C.   +8 more
europepmc   +1 more source

Thianthrenium Salts in Photochemistry. [PDF]

Acc Chem Res
Bai Z, Ritter T.
europepmc   +1 more source

Deaminative methylselenation of anlines with PhSO₂SeCH₃. [PDF]

Front Chem
Wang L, Zhang B, Yan Y, Liu L, Ou G, Xiao N.   +5 more
europepmc   +1 more source

Retraction: Ligand assisted Co(ii) catalyzed direct C-H alkylation of aryl ketones with diverse alkyl halides. [PDF]

Chem Sci
Nigade A, Parmar SV, Avasare V.
europepmc   +1 more source

Aziridinierung eines einzelnen Kohlenstoffatoms in Alkenen mittels Energietransferkatalyse

Angewandte Chemie, EarlyView.
Im Gegensatz zur traditionellen Alken‐Aziridinierung über (formalen) Nitren‐Transfer berichten wir hier über eine Strategie zur intermolekularen Aziridinierung eines einzelnen Alken‐Kohlenstoffatoms bei zusätzlicher Funktionalisierung der anderen Position. Durch Energietransfer‐ (EnT‐)Katalyse werden Alkenylboronate und ‐silane in reaktive Intermediate
Fritz Paulus, Corinna Heusel, Felix H. Wessels, Bünyamin Sikora, Maik G. Niedziella, Kilian van der Beck, Constantin G. Daniliuc, Frank Glorius   +7 more
wiley   +1 more source

Nickel-Catalyzed Aminocarbonylation of Aryl Trifluoromethoxides. [PDF]

Org Lett
Liu ZW, Kuai CS, Wu XF.
europepmc   +1 more source

Modular and Mild Assembly of Aryl Phosphines, Phosphine Oxides/Sulfides, Phosphinates, and Phosphonates Enabled by Photoinduced Divergent Construction of Aryl-P(III) and Aryl-P(V) Bonds. [PDF]

JACS Au
Sun H, Wu D, Yan F, Han Y, Leng J, Jin S, Zhang P, Gu Z, Sui X.   +8 more
europepmc   +1 more source

Photochemical reduction of aryl chlorides, bromides, and iodides <i>via</i> ternary EDA complexes with guanidine bases. [PDF]

Chem Sci
Hannan RJ, Vondran AM, Cho S, Hanson KM, Tonnelé C, Casanova D, Bardeen CJ, Bahamonde A.   +7 more
europepmc   +1 more source

Isolation and Reactivity of a Square‐Planar Trisamido Silane

Angewandte Chemie International Edition, EarlyView.
We report the synthesis and comprehensive characterisation of a square‐planar Si(+IV) hydride supported by an unsymmetric, trianionic and dearomatised N,N,N‐pincer ligand. This system enables element–ligand cooperative reactivity as an alternative to silicon‐centred redox chemistry, illuminating a largely unexplored regime in high‐valent silicon ...
David M. J. Krengel, Xiaobai Wang, Christopher Golz, Regine Herbst‐Irmer, Oliver P. E. Townrow, Malte Fischer   +5 more
wiley   +1 more source