Advances in Ni<sup>I</sup>/Ni<sup>III</sup>-Catalyzed C(sp<sup>2</sup>)-Heteroatom Cross-Couplings. [PDF]
Bena AR, Pieber B.
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The emerging role of aryl hydrocarbon receptor in the activation and differentiation of Th17 cells
Eszter Baricza +4 more
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A stereospecific, transition‐metal‐free SN2 alkylation of cyanohydrins with chiral non‐racemic secondary tosylates is reported, providing efficient access to enantioenriched α‐tertiary ketones. The method exhibits broad substrate scope, operational simplicity, and excellent stereospecificity, including stereoconvergent reactions of E/Z mixtures of ...
Jinjin Ma +3 more
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Ligand assisted Co(ii) catalyzed direct C-H alkylation of aryl ketones with diverse alkyl halides. [PDF]
Nigade A, Parmar SV, Avasare V.
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Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos
We report a new chiral phosphine ligand, sRuPhos, which permits the highly enantioselective Suzuki–Miyaura coupling of ortho‐aniline and ortho‐phenol building blocks. This results in 2‐amino‐2′‐hydroxybiphenyls with very high enantiomeric excesses, products that will have application in pharmaceutical synthesis and ligand design for catalysis ...
Hamzah Sharif +3 more
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Harnessing Pnictogen and Chalcogen Bonding for Cross-Electrophile C-P<sup>III</sup> Coupling of Chlorophosphines with Thianthrenium Salts. [PDF]
Fu GY +5 more
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Antimicrobial Activities of some Synthesized Pyridines, Oxazines and Thiazoles from 3-Aryl-1-(2-naphthyl)prop-2-en-1-ones [PDF]
Salwa F. Mohamed
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Synthesis and Characterization of Unusual S=1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
Despite the long‐standing importance of iron‐silicon bonds as related to catalysis, high‐spin Fe(0)‐silyl complexes remain a historical synthetic challenge in the field. Herein, we report the first series of high‐spin S = 1, styrene‐stabilized Fe(0)‐silyl complexes followed by extensive characterization via Mössbauer spectroscopy, single crystal X‐ray ...
Alexis K. Bauer +2 more
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Controllable copper-catalysed photo-induced carbonylative cyclization to access dihydroquinolinones and oxindoles. [PDF]
Zhao YH, Wang LC, Wu XF.
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