Results 61 to 70 of about 538,570 (408)
The synthesis of 3-aryl-3-trifluoromethyl-2,3-dihydro-1H-pyrrolizin-1-ones
Aim. To develop the efficient method for the synthesis of 3-aryl-3-trifluoromethyl-2,3-dihydro-1H-pyrrolizin-1-ones as promising scaffolds in design of bioactive compounds. Results and discussion.
S. V. Melnykov+4 more
doaj +1 more source
4-Formyl-2-nitrophenyl 3-nitro-2-methylbenzoate [PDF]
In the title formyl nitro aryl benzoate derivative, CH NO, the benzene rings form a dihedral angle of 4.96(3)°. The mean plane of the central ester group, C-O-C-(=O)-C (r.m.s.
Alan R. Kennedy+9 more
core +2 more sources
Organic Synthesis Reaction Involved by Aryl-Triazene As an Arylation Reagent
The aryl-triazene, as an extremely useful and versatile organic synthesis midbody, can be extracted from the aromatic amines in a simple way. This paper mainly describes the arylation reaction between palladium catalysis aryl-triazene and indole and ...
Tingting Ru
doaj +1 more source
An efficient hydrazine substitution of p‐nitro‐aryl fluorides with hydrazine hydrates catalyzed by FeO(OH)@C nanoparticles is described. This hydrazine substitutions of p‐nitro‐aryl fluorides bearing electron‐withdrawing groups proceeded efficiently with
Dingzhong Li+5 more
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An efficient synthesis of novel 1-aryl-3-(indole-3-yl)-3-(2-aryl-1,2,3-triazol-4-yl)propan-1-ones from indoles and 1-aryl-3-(2-aryl-1,2,3-triazol-4-yl)propan-1-one using a Brønsted acid ionic liquid [Sbmim][HSO4] as catalyst is described.
Chuan-Ji Yu, Chen-Jiang Liu
doaj +1 more source
Novel B(Ar')2(Ar'') hetero-tri(aryl)boranes: a systematic study of Lewis acidity [PDF]
A series of homo- and hetero-tri(aryl)boranes incorporating pentafluorophenyl, 3,5-bis(trifluoromethyl)phenyl, and pentachlorophenyl groups, four of which are novel species, have been studied as the acidic component of frustrated Lewis pairs for the ...
Ashley+61 more
core +2 more sources
Nonlinear Optical Response Properties of Aryl - Substituted Boron -Dipyrromethene Dyes: Unidirectional Charge Transfer coupled with Structural Tuning [PDF]
Controlling the nonlinear optical (NLO) response properties at the molecular level is a key to develop strong NLO active materials for technological applications. In this paper, we report quantum chemical investigation of NLO response properties of select aryl-substituted Boron-Dipyrromethene (BODIPY) dyes, a class of intramolecular charge transfer ...
arxiv +1 more source
Enantiomer stability of atropisomeric 1,5-disubstituted 1,2,3-triazoles
The synthesis and characterisation of axially chiral atropisomeric 1,5-disubstituted 1,2,3-triazoles is reported. Molecules designed to display restricted rotation about 1,2,3-triazole N-1-aryl or 1,2,3-triazole C-5-aryl bonds were investigated by ...
Fernanda Meloni+6 more
doaj
Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond formation at palladium [PDF]
This article describes the rational design of 1st generation systems for oxidatively-induced Aryl– CF3 bond-forming reductive elimination from PdII.
Gary, J. Brannon
core +1 more source
Imide and isatin derivatives as β-lactam mimics of β-lactam antibiotics [PDF]
Activated γ-lactams, which are derivatives of succinimide, phthalimide and isatin with suitable elements of molecular recognition, have been synthesised as mimics of the ß-lactam antibiotics and their chemical and biological reactivity ...
Casey, Lorraine A.+4 more
core +1 more source