Results 81 to 90 of about 330,962 (287)

O-Carboxymethyl Chitosan Supported Heterogeneous Palladium and Ni Catalysts for Heck Reaction

open access: yesMolecules, 2017
Two polymer catalysts (Pd-OCMCS and Ni-OCMCS) with good reusability were synthesized by coordinating Pd and Ni onto O-carboxymethyl chitosan (OCMCS). The chemical structure and thermal stability of prepared catalysts were determined by Fourier transform ...
Dongjun Lv, Mingjie Zhang
doaj   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

Pd‐Catalyzed Thiotritylation Cross‐Coupling of Aryl Bromides and Iodides to Access Sulfur Functional Groups

open access: yesChemistryEurope
Sulfur‐containing functional groups (SFGs) are increasingly important for modern medicinal chemistry and their large structural diversity provides many opportunities for lead optimization.
Yue Liu   +3 more
doaj   +1 more source

Mild and facile synthesis of multi-functional RAFT chain transfer agents [PDF]

open access: yes, 2009
In this paper we will describe the synthesis and characterization of a series of novel chain transfer agents for application in reversible addition fragmentation chain transfer polymerization (RAFT).
Hansell, Claire F., O'Reilly, Rachel K.
core   +2 more sources

Hydrogelation via Supramolecular Copolymerization of Structural Water within Adaptive Metal–Organic Fibers

open access: yesAdvanced Materials, EarlyView.
Structural water is harnessed as an active co‐monomer to drive supramolecular polymerization in bulk water. Zinc(II) Salphen complexes confine water molecules to form hollow, metal–organic nanofibers that assemble into adaptive hydrogels with thermoresponsive mechanics and selective chiral recognition.
Merlin R. Stühler   +10 more
wiley   +1 more source

A New Alkylation of Aryl Alcohols by Boron Trifluoride Etherate

open access: yesMolecules, 2019
The ethylation of aryl alcohols by an ethyl moiety of boron trifluoride etherate is described. The reaction proceeded cleanly and afforded good yields of the corresponding aryl ethyl ethers.
Ndze Denis Jumbam   +5 more
doaj   +1 more source

Photoinitiated oxidative addition of CF3I to gold(I) and facile aryl-CF3 reductive elimination. [PDF]

open access: yes, 2014
Herein we report the mechanism of oxidative addition of CF3I to Au(I), and remarkably fast Caryl-CF3 bond reductive elimination from Au(III) cations. CF3I undergoes a fast, formal oxidative addition to R3PAuR (R = Cy, R = 3,5-F2-C6H4, 4-F-C6H4, C6H5, 4 ...
TOSTE, F. Dean   +2 more
core   +1 more source

Peripheral Arylation of Subporphyrazines

open access: yesChemistry – A European Journal, 2013
AbstractPeripherally hexaarylated subporphyrazines (SubPzs) have been prepared through a Pd‐catalyzed, CuTC‐mediated coupling of a hexaethylsulfanylated subporphyrazine with arylboronic acids. The introduced aryl substituents strongly influence the electronic properties of the subporphyrazine through effective conjugative interaction.
Higashino T.   +3 more
openaire   +3 more sources

Understanding Operando Water Management in Hydroxide‐Exchange‐Membrane Fuel Cells

open access: yesAdvanced Materials Interfaces, EarlyView.
Effective water management is vital for high‐performance hydroxide‐exchange‐membrane fuel cells. Using a custom water‐flux station, this study quantifies how membrane thickness, microporous layers, and operating conditions dictate internal water transport.
Catherine M. Weiss   +4 more
wiley   +1 more source

One-pot near-ambient temperature syntheses of aryl(difluoroenol) derivatives from trifluoroethanol [PDF]

open access: yes, 2011
Difluoroalkenylzinc reagents prepared from 1-(2’-methoxy-ethoxymethoxy)-2,2,2-trifluoroethane and 1-(N,N-diethylcarbamoyloxy)-2,2,2-trifluoroethane at ice bath temperatures, underwent Negishi coupling with a range of aryl halides in a convenient one pot ...
Kyne, Sara H   +4 more
core   +1 more source

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