Results 231 to 240 of about 257,949 (316)

Catalytic Antioxidant Activity of Acyclic and Macrocyclic Selenides: Insights Into Structure–Activity Relationships and Mechanisms From Kinetic and Computational Studies

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Structure–activity relationships of antioxidant activities of selenides were established by experimental and computational methods. Several structures displayed strong catalytic activity in an NMR‐based assay. Diverse selenides were shown to act as potent catalytic antioxidants.
Adrian I. Doig, Wen Zhou, Thomas G. Back
wiley   +1 more source

Planarized and Twisted Intramolecular Charge Transfer: Small Geometric, Huge Photophysical Changes

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Molecular motion governs excited state relaxation in aminobenzonitrile donor–acceptor systems. Small structural modifications control single and dual rotations and enable distinct relaxation pathways. Fluorescence spectroscopy, Lippert–Mataga analysis, and theoretical calculations identify multiple excited states, including a dual‐emitting planarized ...
Zoe Nonie Scheller   +2 more
wiley   +1 more source

Glymphatic dysfunction couples with cortical excitation–inhibition imbalance in epilepsy: Evidence from Rasmussen encephalitis

open access: yesEpilepsia, EarlyView.
Cong Fu et al. demonstrate that glymphatic system dysfunction is linked to enhanced inhibitory cortical activity using diffusion MRI and EEG. These findings highlight a mechanistic link between perivascular fluid dynamics and neuronal activity, suggesting a role for glymphatic function in maintaining cortical stability in epilepsy.
Cong Fu   +11 more
wiley   +1 more source

Ultrafast oscillations in the human brain and their functional significance

open access: yesEpilepsia, EarlyView.
Abstract Objective The upper frequency limit of human brain activity remains unknown. Using ultrahigh sampling rate (≥20 kHz) intracranial microelectroencephalography, this study aimed to systematically explore and quantitatively characterize brain field oscillations beyond the established high‐frequency oscillation range (>2 kHz), and to determine ...
Milan Brázdil   +13 more
wiley   +1 more source

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