ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp [PDF]
Polym. Chem., 2014 We report on photoinduced ATRP in solution and from surfaces using a standard fluorescent lamp as the light source.
Zhang, Tao +3 more
core +6 more sources
Kinetic Modeling of ICAR ATRP [PDF]
Macromolecular Theory and Simulations, 2011 AbstractKinetic modeling is used to better understand and optimize initiators for continuous activator regeneration atom‐transfer radical polymerization (ICAR ATRP). The polymerization conditions are adjusted as a function of the ATRP catalyst reactivity for two monomers, methyl methacrylate and styrene.
Dagmar R. D'hooge +4 more
openaire +3 more sources
Progress in the Design and Application of Chemical and Biological Sensors Based on Atom Transfer Radical Polymerization [PDF]
BiosensorsAtom transfer radical polymerization (ATRP) is a leading reversible deactivation radical polymerization method. It has become an emerging technology to synthesize well-defined, tailor-made polymers, promoting the development of advanced materials (e.g ...
Ning Xia +4 more
doaj +2 more sources
ATRP in the design of functional materials for biomedical applications [PDF]
Progress in Polymer Science, 2012 Atom Transfer Radical Polymerization (ATRP) is an effective technique for the design and preparation of multifunctional, nanostructured materials for a variety of applications in biology and medicine. ATRP enables precise control over macromolecular structure, order, and functionality, which are important considerations for emerging biomedical designs.
Siegwart, Daniel J. +2 more
openaire +6 more sources
Scalable Air-Tolerant μL-Volume Synthesis of Thick Poly(SPMA) Brushes Using SI-ARGET-ATRP [PDF]
, 2023 We present a facile procedure for preparing thick (up to 300 nm) poly(3-sulfopropyl methacrylate) brushes using SI-ARGET-ATRP by conducting the reaction in a fluid film between the substrate and a coverslip.
Sissi de Beer (7846298) +3 more
core +1 more source
A Comparative Study between FRP and ATRP of Styrene by Monte Carlo Simulation: Effect of Free Radical Mobility [PDF]
علوم و تکنولوژی پلیمر, 2010 Styrene polymerization through FRP and ATRP methods was carried out at 110oC, while in-depth studies were performed by Monte Carlo simulation.The changes in monomer conversion, initiator concentration, average molecular weight, and polydispersity index ...
M. Najafi +3 more
doaj +1 more source
Study of Atom Transfer Radical Polymerization of Styrene and Its Gel Effect by Monte Carlo Simulation Method [PDF]
علوم و تکنولوژی پلیمر, 2009 Atom transfer radical polymerization (ATRP) of styrene was carried out at 105°C and a Monte Carlo simulation was employed to model the system. The variations of monomer conversion, the initiator concentration, average molecular weight, and molecular ...
M. Najafi +3 more
doaj +1 more source
Disproportionation or Combination? The Termination of Acrylate Radicals in ATRP [PDF]
Macromolecules, 2017 The termination of acrylate radicals in atom transfer radical polymerization (ATRP) can involve either conventional bimolecular radical termination (RT) or catalytic radical termination (CRT). These processes were investigated using a poly(methyl acrylate)–Br macroinitiator under different initial conditions tuned to change the RT/CRT ratio.
Thomas G. Ribelli +5 more
openaire +3 more sources
Effect of Polymerization Components on Oxygen-Tolerant Photo-ATRP [PDF]
, 2019 Photo-ATRP has recently emerged as a powerful technique that allows for oxygen-tolerant polymerizations and the preparation of polymers with low dispersity and high end-group fidelity.
Daniel Messmer +11 more
core +1 more source
PVDF-Based Fluoropolymer Modifications via Photoinduced Atom Transfer Radical Polymerizations
Advances in Polymer Technology, 2022 Graft modifications of PVDF fluoropolymers have been identified as the efficient route to improve the properties and expand the applications. Taking advantage of C-F and C-Cl bonds in the repeat units, atom transfer radical polymerizations (ATRP) were ...
Nuo Xu +12 more
doaj +1 more source