Results 31 to 40 of about 10,606 (223)

In-situ preparation of triazole polymerization films on copper surface via SI-ATRP method and their performance against copper corrosion

open access: yesJournal of Materials Research and Technology, 2023
As one of the most advanced film forming technologies, the surface-initiated controlled/living radical polymerization provides an effective method for in-situ fabricating functional films on material surface.
Chun-ping Li   +5 more
doaj   +1 more source

Photoinitiated ATRP in Inverse Microemulsion

open access: yesMacromolecules, 2013
The recently developed photoinitiated atom transfer radical polymerization has been implemented in the inverse microemulsion polymerization of oligo(ethylene glycol) monomethyl ether methacrylate. Two different mechanisms including a simultaneous reverse and normal initiated ATRP and a combination of activators generated by electron transfer and ...
Ciftci, Mustafa   +4 more
openaire   +2 more sources

An Acid Test: Facile SI-ARGET-ATRP of Methacrylic Acid [PDF]

open access: yes, 2018
Atom transfer radical polymerization (ATRP) of methacrylic acid (MAA) is challenging. Herein is reported a study of conditions for facile surface-initiated ATRP by activator regenerated electron transfer (SI-ARGET-ATRP) growth of poly-methacrylic acid ...
Jung, Dimitri   +19 more
core   +1 more source

Toward Green Atom Transfer Radical Polymerization: Current Status and Future Challenges

open access: yesAdvanced Science, 2022
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with controlled architecture, composition, and functionality.
Sylwia Dworakowska   +3 more
doaj   +1 more source

Comparative Study of Polymer-Grafted BaTiO3 Nanoparticles Synthesized Using Normal ATRP as Well as ATRP and ARGET-ATRP with Sacrificial Initiator with a Focus on Controlling the Polymer Graft Density and Molecular Weight

open access: yesMolecules, 2023
Structurally well-defined polymer-grafted nanoparticle hybrids are highly sought after for a variety of applications, such as antifouling, mechanical reinforcement, separations, and sensing.
Ikeoluwa E. Apata   +5 more
doaj   +1 more source

Electrochemically mediated atom transfer radical polymerization in the presence of oxygen [PDF]

open access: yes, 2022
openSi svilupperà un metodo elettrochimico che sfrutta la riduzione elettrocatalitica di O 2 ad H 2 O, in ambiente acquoso, per rimuovere l’ossigeno dall’ambiente di polimerizzazione radicalica per trasferimento di atomo (ATRP).
ANTONELLO, ANDREA
core  

Macromolecular Engineering by Applying Concurrent Reactions with ATRP [PDF]

open access: yesPolymers, 2020
Modern polymeric material design often involves precise tailoring of molecular/supramolecular structures which is also called macromolecular engineering. The available tools for molecular structure tailoring are controlled/living polymerization methods, click chemistry, supramolecular polymerization, self-assembly, among others.
Yu Wang   +2 more
openaire   +2 more sources

Exploring Electrochemically Mediated ATRP of Styrene [PDF]

open access: yesProcesses, 2021
Electrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties of various Cu(II) species were investigated in CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both in the absence and presence of 50% (v/v ...
Francesco De Bon   +3 more
openaire   +2 more sources

Kinetics of Fe-Mediated ATRP with Triarylphosphines [PDF]

open access: yes, 2015
Phosphines have been successfully used as additives for Fe-based ATRP. To understand their role in detail, the kinetics of Fe-based ATRP in the presence of tris(2,4,6-trimethoxyphenyl)-phosphine (TTMPP) and of triphenylphosphine (TPP) was studied via ...
Matyjaszewski, Krzysztof   +2 more
core   +3 more sources

Oxygen‐Tolerant Photo‐Induced Miniaturized Accelerated Atom Transfer Radical Polymerization (OPTIMA‐ATRP) for High‐Throughput Synthesis of Polymer Bioconjugates

open access: yesAngewandte Chemie, EarlyView.
Oxygen‐tolerant photo‐induced miniaturized accelerated atom transfer radical polymerization (OPTIMA‐ATRP) in water was developed for the polymerization of hydrophilic (meth)acrylate monomers under ambient or sub‐ambient (4°C) temperature and atmospheric conditions, without prior degassing, in less than 10 min, at an ultra‐small scale (< 50 µL) in ...
Arman Moini Jazani   +5 more
wiley   +2 more sources

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