Preparation and Characterization of Hyperbranched Polystyrene Nanocomposite Synthesized by Living Radical Polymerization and Solution Intercalation Method [PDF]
علوم و تکنولوژی پلیمر, 2013 A copolymer of styrene and methyl styrene was synthesized by nitroxide - mediated “living” free radical polymerization )NMP). N-Bromosuccinimide was used as a brominating agent to obtain a copolymer with bromine as its end group.
Mojtaba Abbasian +3 more
doaj +1 more source
Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis
Chemical Science, 2022 Photoinduced atom transfer radical polymerization (photo-ATRP) has risen to the forefront of modern polymer chemistry as a powerful tool giving access to well-defined materials with complex architecture. However, most photo-ATRP systems can only generate
Grzegorz Szczepaniak +9 more
semanticscholar +1 more source
Preparation of Polystyrene Nanocomposite by In Situ Atom Transfer Radical Polymerization: Study of Polymerization Kinetics in the Presence of Clay [PDF]
علوم و تکنولوژی پلیمر, 2009 Styrene nanocomposites were synthesized by in-situ atom transfer radical polymerization at 110oC. The variations of monomer conversion and the linearity of semilogarithmic kinetic plot, some signs of living polymerizationand constant radical ...
H. Roghani-Mamaqani +3 more
doaj +1 more source
Iron Catalysts in Atom Transfer Radical Polymerization
Molecules, 2020 Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of ...
Sajjad Dadashi-Silab +1 more
doaj +1 more source
A Comparative Study between FRP and ATRP of Styrene by Monte Carlo Simulation: Effect of Free Radical Mobility [PDF]
علوم و تکنولوژی پلیمر, 2010 Styrene polymerization through FRP and ATRP methods was carried out at 110oC, while in-depth studies were performed by Monte Carlo simulation.The changes in monomer conversion, initiator concentration, average molecular weight, and polydispersity index ...
M. Najafi +3 more
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Inhibiting the Thermal Gelation of Copolymer Stabilized Nonaqueous Dispersions and the Synthesis of Full Color PMMA Particles [PDF]
, 2016 Polymeric particle dispersions have numerous potential applications; currently one of the most relevant is their use as inks in electrophoretic displays.
Simon J. Holder (1866523) +7 more
core +1 more source
Advances in Organocatalyzed Atom Transfer Radical Polymerization
Advances in Polymer Technology, 2019 Atom transfer radical polymerization (ATRP) is one of the most robust tools to prepare well-defined polymers with precise topologies and architectures. Although series of improved ATRP methods have been developed to decrease the metal catalyst loading to
Xin Hu, Ning Zhu, Kai Guo
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Effect of Reactant Concentration Variations on the Kinetics of Atom Transfer Radical Polymerization of Acrylonitrile [PDF]
علوم و تکنولوژی پلیمر, 2013 Polyacrylontrile synthesis, via atom transfer radical polymerization, is studied in various initiator concentrations, transitional metal catalyst and different concentrations of CuBr2.
H. Roghani-Mamaqani +3 more
doaj +1 more source
Results in Materials, 2022 Supplementary techniques to atom transfer radical polymerization (ATRP) have been studied to reduce the concentration of catalytic complexes used, aiming at a less costly and more environmentally friendly process for synthesizing polymeric materials ...
Guilherme C.L. Faria, Emerson P. Lyra
doaj +1 more source
Toward Green Atom Transfer Radical Polymerization: Current Status and Future Challenges
Advanced Science, 2022 Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with controlled architecture, composition, and functionality.
Sylwia Dworakowska +3 more
doaj +1 more source