ATRP with ppb Concentrations of Photocatalysts
In atom transfer radical polymerization (ATRP), dormant alkyl halides are intermittently activated to form growing radicals in the presence of a CuI/L/X-CuII/L (activator/deactivator) catalytic system. Recently developed very active copper complexes could decrease the catalyst concentration to ppm level. However, unavoidable radical termination results
Halil Ibrahim Coskun +6 more
openaire +2 more sources
Molecular imprinting for neurology: Materials, applications, and limitations
Molecularly imprinted materials: diagnostic, therapeutic and research applications in neurology. Molecularly imprinted materials offer high specificity and affinity for target molecules in neurological applications. This review highlights their synthesis, characterisation, and use in diagnostics, research and therapeutics.
Xiaohan Ma +3 more
wiley +1 more source
Abstracting Asynchronous Multi-Valued Networks: An Initial Investigation [PDF]
Multi-valued networks provide a simple yet expressive qualitative state based modelling approach for biological systems. In this paper we develop an abstraction theory for asynchronous multi-valued network models that allows the state space of a model to
Steggles, L. Jason
core +1 more source
Creating the Technopolis: High-Technology Development in Austin, Texas [PDF]
New institutional alliances, driven by the rapid increase in and diversity of new technologies, are altering the strategy and tactics of economic development.
Gibson, David V. +2 more
core +1 more source
3D Polymeric Nanonetworks: From Self‐Assembly to Advanced Fabrication
This review provides the first systematic cross‐method comparison of fabrication techniques for 3D polymeric nanonetworks. It evaluates five key strategies—block copolymer self‐assembly, hyper‐crosslinking, template‐assisted methods, 3D printing, and nanolithography—across critical metrics including resolution, throughput, scalability, and material ...
Carlos G. Cobos +2 more
wiley +1 more source
Atom Transfer Radical Polymerization of Styrene in Presence of Mesoporous Silica Nanoparticles: Application of Reverse, Simultaneous Reverse and Normal Initiation Techniques [PDF]
Atom transfer radical polymerization (ATRP) of styrene in presence of mesoporous silica nanoparticles was carried out at 110 °C. Reverse atom transfer radical polymerization (RATRP) and simultaneous reverse and normal initiation for atom transfer radical
Khezrollah Khezri +3 more
doaj +1 more source
Copper mediated reversible deactivation radical polymerization in aqueous media [PDF]
Key advances within the past 10 years have transformed copper mediated radical polymerization from a technique which was not very tolerant to protic media into a range of closely related processes capable of control over the polymerization of a wide ...
Anastasaki, Athina +5 more
core +1 more source
Mechanophoric 3‐Arm Star Functional Block Copolymer Based on Rhodamine Derivative
Mechanoresponsive rhodamine containing linear and star block and random copolymers were synthesized and characterized. All materials transitioned into a “switch‐on” state in the film form, but only the star block copolymer architecture exhibited a complete and precise peak shift upon stretching, providing new insights into the mechanochemical ...
Swadhin Chakraborty +8 more
wiley +1 more source
Diazirines are three‐membered, nitrogen‐containing heterocycles that decompose under light or heat to generate carbenes. For the past two decades, they have served mainly as minimally invasive tags in photoaffinity labeling (PAL). More recently, their value as versatile carbene precursors has been recognized.
Dominik Schnalzer +4 more
wiley +2 more sources
Designer ligands: The search for metal ion selectivity
The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as ...
Perry Kaye
doaj

