Synthesis of homo- and copolymer containing sulfonic acid via atom transfer radical polymerization
Designed Monomers and Polymers, 2022 Well-defined functional poly(p-phenyl styrenesulfonate) and poly(p-phenyl styrene-sulfonate-co-styrene) were successfully synthesized by the atom transfer radical polymerization (ATRP) using CuBr/bpy(PMDETA) catalyst and 1-phenylethyl bromide (1-PEBr) as
Md. Wali Ullah +4 more
doaj +1 more source
“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres [PDF]
, 2010 Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e.
Calberg, Cédric +3 more
core +1 more source
Abstracting Asynchronous Multi-Valued Networks: An Initial Investigation [PDF]
, 2011 Multi-valued networks provide a simple yet expressive qualitative state based modelling approach for biological systems. In this paper we develop an abstraction theory for asynchronous multi-valued network models that allows the state space of a model to
Steggles, L. Jason
core +1 more source
Polymer brush collapse under shear flow
, 2017 Shear responsive surfaces offer potential advances in a number of applications. Surface functionalisation using polymer brushes is one route to such properties, particularly in the case of entangled polymers.
Adlmann, Franz A. +8 more
core +3 more sources
Direct introduction of nitrogen and oxygen functionality with spatial control using copper catalysis. [PDF]
, 2018 Synthetic chemists have spent considerable effort optimizing the synthesis of nitrogen and oxygen containing compounds through a number of methods; however, direct introduction of N- and O-functionality remains challenging.
Fisher, David J +4 more
core
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications [PDF]
, 2015 The use of light to mediate controlled radical polymerization has emerged as a powerful strategy for rational polymer synthesis and advanced materials fabrication.
Chen, Mao +2 more
core +1 more source
Design, Synthesis and Architectures of Hybrid Nanomaterials for Therapy and Diagnosis Applications [PDF]
, 2018 Hybrid nanomaterials based on inorganic nanoparticles and polymers are highly interesting structures since they combine synergistically the advantageous physical-chemical properties of both inorganic and polymeric components, providing superior ...
Biglione, Catalina +2 more
core +1 more source
Robust Artificial Polyenzyme for Recyclable Pickering Emulsion and Cascade Synthesis
ChemCatChem, EarlyView.Artificial polyenzyme (ArPoly) forms amphiphilic proteinpolymer conjugates that stabilize Pickering emulsions with tunable interfacial properties for biocatalysis. These emulsions enable efficient and robust single‐step reactions, multi‐step biocatalytic cascades, and whole‐cell catalysis.
Shan Wang, Changzhu Wu
wiley +1 more source
Designer ligands: The search for metal ion selectivity
South African Journal of Science, 2011 The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as ...
Perry Kaye
doaj
Fibers, 2015 Surface-initiated graft atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) from self-assembled chitin nanofibers (CNFs) was performed under dispersion conditions.
Ryo Endo +2 more
doaj +1 more source