ATRP-based polymers with modular ligation points under thermal and thermomechanical stress [PDF]
Linear polystyrenes carrying a mid-chain triazole, esters as well as terminal secondary bromines functionalities were synthesized via activators regenerated by electron transfer (ARGET) atom transfer radical polymerization (ATRP) using a bifunctional ...
De Winter, J. +7 more
core +2 more sources
Tailored for Binding: Alanine‐Modified Poly(1‐Naphthylamine) Targets Serum Albumins
Alanine modified poly(1‐naphthylamine). ABSTRACT This study presents a new approach for modifying the structural and functional properties of poly(1‐naphthylamine) (PNA) by incorporating the amino acid alanine (Ala) in different molar proportions (80/20, 50/50, and 20/80 for PNA/Ala) through an ultrasound‐assisted polymerization process.
Nuzhat Nabi, Ufana Riaz
wiley +1 more source
Why Do We Need More Active ATRP Catalysts?
Atom transfer radical polymerization (ATRP) is a staple technique for the preparation of polymers with well-defined architecture. In ATRP, the catalyst governs the equilibrium between propagating radicals and dormant species, thus affecting the ...
Francesca Lorandi +3 more
core +1 more source
Synthesis and characterization of novel polysiloxane based ABA-type triblock copolymers using ATRP
Novel polysiloxane based ABA-type triblock copolymers having a secondary amine at the junction point were synthesized using a combination of ring opening equilibration polymerization (ROEP), Michael addition and atom transfer radical polymerization (ATRP)
Bodkhe Rajan B., Webster Dean C.
doaj +1 more source
Diverse reactivity of maleimides in polymer science and beyond
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source
ATRP poly(acrylate) star formation: a comparative study between MALDI and ESI mass spectrometry
Optimised matrix-assisted laser desorption/ionisation (MALDI) and electrospray ionisation (ESI) mass spectrometry (MIS) methodologies were systematically compared in terms of their relative abilities to identify distinct chemical species present in ...
Du Prez, Filip +9 more
core +1 more source
Synthesis of Poly(Itaconate)s With High Monomer Conversion Applying Emulsion Polymerization
Itaconic acid and its derivatives are a promising and bio‐based substitute for oil‐based polymers such as acrylates. In this study, the optimization of polymerization of itaconic acid esters is described by applying emulsion polymerization leading to high reaction conversions and low residual monomer contents. ABSTRACT Itaconic acid and its derivatives
S. Charlotte Fischer von Mollard +5 more
wiley +1 more source
Emulsifying Property and Emulsifying Stability of Alkali Extracted Tea Residue Protein
The alkali-extracted tea residue protein (ATRP) is a novel protein resource with the potential to become a food-grade emulsifier. This study assessed ATRP's emulsion type and hydrophilic-lipophilic balance value, analyzed the effects of various ...
Shengyu ZHANG +4 more
doaj +1 more source
Horan et al. demonstrate that RGD peptide‐functionalized poly(ethylene glycol) brush films synthesized in polydimethylsiloxane microfluidic channels by surface‐initiated atom transfer radical polymerization enable label‐free separation of melanoma and ovarian cancer cells based on differential integrin expression.
Stephen Horan +6 more
wiley +1 more source
Recent advances in polymeric chemically amplified positive resists: Materials and design strategies
This review summarizes recent advances in the molecular design of positive chemically amplified resists, focusing on photoacid generators and polymer architectures. Key strategies for enhancing sensitivity—including self‐amplification effects, copolymerization of sensitive monomers, controlled polymerization, and photosensitized chemically amplified ...
Litao Zhou +3 more
wiley +1 more source

