Results 71 to 80 of about 10,606 (223)

Synthesis of homo- and copolymer containing sulfonic acid via atom transfer radical polymerization

open access: yesDesigned Monomers and Polymers, 2022
Well-defined functional poly(p-phenyl styrenesulfonate) and poly(p-phenyl styrene-sulfonate-co-styrene) were successfully synthesized by the atom transfer radical polymerization (ATRP) using CuBr/bpy(PMDETA) catalyst and 1-phenylethyl bromide (1-PEBr) as
Md. Wali Ullah   +4 more
doaj   +1 more source

A modular and programmable electrolyte platform: Covalently anchored thermochromic hydrogels for on‐demand electrochromic devices

open access: yesFlexMat, EarlyView.
Developing stable, multifunctional hydrogel electrolytes without compromising performance presents a considerable challenge in the field. In this study, we introduce a material design strategy with broad applicability to combinations of functional polymeric segments, ionic monomers, and salts.
Manyu Liu   +7 more
wiley   +1 more source

ATRP Grafting from Gel Coated Microspheres [PDF]

open access: yes, 2004
Swellable microspheres prepared by the precipitation polymerisation of divinylbenzene-80 (DVB-80) and 2-hydroxyethyl methacrylate (HEMA), in a solvent mixture of methyl ethyl ketone (MEK) and heptane, were functionalised with 2bromopropionyl bromide ...
Robinson, Erica
core  

Interface Engineering of Boron Nitride–Polymer Composites for High Thermal Conductivity

open access: yesInformation &Functional Materials, EarlyView.
This review comprehensively discusses the impacts of interfacial design and fabrication strategies on boron nitride–polymer composites, and systematically classifies and summarizes recent advances in interfacial engineering based on the interaction modes between boron nitride fillers and polymer matrices.
Zhao Chen   +4 more
wiley   +1 more source

Designer ligands: The search for metal ion selectivity

open access: yesSouth African Journal of Science, 2011
The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as ...
Perry Kaye
doaj  

Multi‐Responsive PAA/PNIPAM Semi‐IPN Hydrogel Properties Controlled by PAA Topology

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymer topology governs hydrogel behavior in semi‐interpenetrating networks. Cyclic poly(acrylic acid) enables controlled pH‐responsive swelling, improved stability, and enhanced deformability compared to linear analogues, while linear systems show higher strength during thermal de‐swelling.
Suraj Aswale   +7 more
wiley   +1 more source

Modulating the Swelling Behavior of Polymer Brushes via Interfacial Chemistry

open access: yesAngewandte Chemie, Volume 138, Issue 29, 13 July 2026.
Modulating substrate surface chemistry of surface‐grafted polymer brushes via variation of the chemical composition of spacers that anchor initiators for surface‐initiated atom transfer polymerizations allows to tune swelling of these thin polymer films.
Kuljeet Kaur   +4 more
wiley   +2 more sources

Atom Transfer Radical Polymerization of Styrene in Presence of Mesoporous Silica Nanoparticles: Application of Reverse, Simultaneous Reverse and Normal Initiation Techniques [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2014
Atom transfer radical polymerization (ATRP) of styrene in presence of mesoporous silica nanoparticles was carried out at 110 °C. Reverse atom transfer radical polymerization (RATRP) and simultaneous reverse and normal initiation for atom transfer radical
Khezrollah Khezri   +3 more
doaj   +1 more source

Synthesis and Characterization of Acrylate‐Based Block and Block‐Graft Copolymers Using Polyester‐Based Macro‐RAFT Agents Through Two‐Step Polymerization and Assessment of One‐Pot Epoxy Group Ring‐Opening Modification

open access: yesPolymer Engineering &Science, EarlyView.
Schematic diagram of RAFT polymerization of acrylate monomers. ABSTRACT This study reports the synthesis of a macro‐RAFT agent based on poly(ɛ‐caprolactone) (PCL) via ring‐opening polymerization (ROP), which was subsequently used to prepare acrylate‐based block and block‐graft copolymers through RAFT polymerization.
Melahat Göktaş, Cengiz Aykaç
wiley   +1 more source

How are Radicals (Re)Generated in Photochemical ATRP? [PDF]

open access: yes, 2016
The polymerization mechanism of photochemically mediated Cu-based atom-transfer radical polymerization (ATRP) was investigated using both experimental and kinetic modeling techniques. There are several distinct pathways that can lead to photochemical (re)
Stefan Bernhard (364854)   +3 more
core   +1 more source

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