Results 101 to 110 of about 22,019 (267)

Data in support of dual-functionalized cellulose nanofibrils prepared through TEMPO-mediated oxidation and surface-initiated ATRP

open access: yesData in Brief, 2015
We previously studied a suitably 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose nanofibrils (TOCNs) that can be further functionalized with initiating sites and overcame the obstacle of performing atom transfer radical polymerization ...
Tzung-Yung Tsai, Chih-Feng Huang
doaj   +1 more source

ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp

open access: yes, 2014
Photoinduced atom transfer radical polymerization (ATRP) was achieved using a simple household fluorescent lamp as the light source. In solution, methyl methacrylate could be polymerized to well-defined polymers; the photoinduced ATRP system did only ...
Amin, Ihsan   +3 more
core  

An Inimer Approach Based on Photo Iniferter RAFT Polymerization Toward One‐Pot Bottlebrush Copolymers Featuring Grafts From Less Activated Monomers

open access: yesJournal of Polymer Science, EarlyView.
We present a stepwise one‐pot synthesis of bottlebrush copolymers using the inimer approach for less activated monomers (LAMs). Under the irradiation of wavelength 1 (λ1), an acrylamide‐based inimer was polymerized to create a backbone with active sites for grafting.
Lucía Diez‐Caballero   +5 more
wiley   +1 more source

Polymer brushes for antibiofouling and lubrication

open access: yesBiosurface and Biotribology, 2017
Surface-initiated atom transfer radical polymerization (SI-ATRP) could provide many merits for the preparation of polymer brush, such as the well-defined chemical configurations, gradient, architecture and thickness.
Wufang Yang, Feng Zhou
doaj   +1 more source

Rational Design and Development of Organic Afterglow Nanoparticles for Image‐Guided Interventions

open access: yesSmall Methods, EarlyView.
This review outlines the rational design, synthesis, and standardized characterization of organic afterglow nanoparticles for biomedical imaging and therapy. Mechanistic insights into chemically initiated electron exchange luminescence and reactive oxygen species‐mediated processes are connected to molecular engineering and nanoparticle fabrication ...
Asma Harun   +6 more
wiley   +1 more source

Synthesis of novel glycopolymer brushes via a combination of RAFT-mediated polymerisation and ATRP

open access: yesSouth African Journal of Science, 2011
Glycopolymers (synthetic sugar-containing polymers) have become increasingly attractive to polymer chemists because of their role as biomimetic analogues and their potential for commercial applications.
Reda Fleet   +2 more
doaj  

Synthesis of Patchy Particles at Phase Boundaries

open access: yesSmall Methods, EarlyView.
The various strategies employed for synthesizing complex multifunctional patchy particles are reviewed, with, as a guideline, the type of phase boundary (solid‐gas, liquid‐gas, solid‐liquid, and liquid‐liquid), that serves as the crucial ingredient for symmetry breaking.
Lin Zhang, Alexander Kuhn
wiley   +1 more source

ATRP poly(acrylate) star formation: a comparative study between MALDI and ESI mass spectrometry

open access: yes, 2009
Optimised matrix-assisted laser desorption/ionisation (MALDI) and electrospray ionisation (ESI) mass spectrometry (MIS) methodologies were systematically compared in terms of their relative abilities to identify distinct chemical species present in ...
Du Prez, Filip   +9 more
core   +1 more source

Designing Tailored Molecular Cavities Using Calix[5]arenes as Building Blocks

open access: yesThe Chemical Record, EarlyView.
This account focuses on the shape and dimensions of cavities formed by precisely designed molecular frameworks. It highlights our efforts to construct synthetically tailored cavities based on calix[5]arenes. This study examines the shapes and dimensions of cavities defined by well‐designed molecular structures.
Takehiro Hirao, Takeharu Haino
wiley   +1 more source

Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications

open access: yesThe Chemical Record, EarlyView.
Thermally stable photoswitches offer new opportunities for controlling polymer structures and functions under nonequilibrium conditions. This Personal Account highlights stiff stilbene (SS) and sterically hindered stiff stilbene (HSS) photoswitches, which combine large structural changes with exceptional thermal bistability.
Keiichi Imato
wiley   +1 more source

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