Results 151 to 160 of about 69,209 (245)

Stabilization of Strongly Reduced Fe(I) Single Atom Species Coordinated in a 2D Self‐Assembled Metal–Organic Network

Advanced Functional Materials, EarlyView.
A graphene‐supported 2D metal–organic network stabilizes highly reactive Fe(I)‐N4 single sites through Co‐induced charge redistribution. Combined experiments and theory reveal Fe(I) formation, oxygen‐driven oxidation, and O2 activation mechanisms, offering a strategy to access low‐valent iron centers relevant to catalytic and biological processes ...
Alessandro Namar, Basant Roondhe, Michela De Col, Stefania Baronio, Matteo Jugovac, Mattia Scardamaglia, Eleanor Frampton, Nikolay Vinogradov, Paolo Giannozzi, Erik Vesselli   +9 more
wiley   +1 more source

Ga–O–Pt Electronic Bridges Bypass Single‐Site Constraints for pH‐Universal Hydrogen Evolution

Advanced Functional Materials, EarlyView.
Well‐defined oxygen‐bridged Ga–O–Pt catalysts are constructed for pH‐universal hydrogen evolution, highlighting the relationship between oxygen‐bridged electronic coupling, rapid surface hydrogen redistribution, and superior catalytic performance. ABSTRACT Single‐site descriptors often fail to capture hydrogen evolution on heterometallic interfaces ...
Rui Wang, Jinbo Sun, Nicole L. D. Sui, Zitao Li, Jie Chen, Shulai Lei, Yuntong Sun, Wenjun Fan, Jong‐Min Lee   +8 more
wiley   +1 more source

Elucidating the Role of NaCl in the on-Surface Synthesis of Conjugated Azaacene Polymers on Au(111). [PDF]

Chemistry
Kratky T, Liu X, Günther S, Mutombo P, Schio L, Schio L, Floreano L, Decurtins S, Repp J, Jelínek P, Liu SX, Patera LL.   +11 more
europepmc   +1 more source

Role of Structural Disorder on Phonon Transport and Thermal Conductivity in Li6PS5Br

Advanced Functional Materials, EarlyView.
Solid electrolytes are fast ion and slow heat conductors. Although both transport properties are governed by lattice dynamics and atomic structure, their interplay remains poorly understood. Here, we study this interrelation in anion‐ordered and disordered Li6PS5Br.
Lukas Ketter, Ryoma Sasaki, Kyra Strotmann, Wolfgang G. Zeier, Yoshitaka Tateyama   +4 more
wiley   +1 more source

Landing-Energy-Controlled Surface Conformation of Electrosprayed Foldamer Molecules on Au(111). [PDF]

ACS Nano
Zhang S, Meier D, Lawes P, Zhao P, Wang J, Maurizot V, Walz A, Huettig A, Schlichting H, Papageorgiou AC, Reichert J, Huc I, Barth JV.   +12 more
europepmc   +1 more source

Intracrystalline Void‐Mediated Toughening of Brittle Crystals in Quail Eggshells

Advanced Functional Materials, EarlyView.
In quail eggshells, the high density and disordered arrangement of intracrystalline voids inhibit lattice cleavage, suppress long‐range crack propagation, and promote deformation twinning and quasi‐plasticity, serving as an essential toughening motif. We show that these voids remain within a narrow subcritical size range and therefore predominantly do ...
Jingxiao Zhong, Qihang Wang, Andre E. Vellwock, Sinuhe Perea Puente, Tingting Zhu, Jia Hui Lim, Kadda Medjoubi, Sebastian Hoerl, Erika Griesshaber, Wolfgang W. Schmahl, Yannicke Dauphin, Emeline Raguin, Peter Werner, Francesco Stellacci, Michael V. Swain, Peter Fratzl, Shahrouz Amini   +16 more
wiley   +1 more source

Symmetry-Selective Ultrafast Charge Transfer via Cyano End Groups at the PDIF-CN₂-Au(111) Interface. [PDF]

Nano Lett
Kladnik G, Cassinese A, Schio L, Goldoni A, Morgante A, Floreano L, Cvetko D.   +6 more
europepmc   +1 more source

GeS as an Emerging OTS Material: Atomic Structure and Modeling of ON/OFF Switching

Advanced Functional Materials, EarlyView.
The structural puzzle of glassy GeS, an advanced memory‐selector material, has finally been disentangled, revealing a patchwork of mixed tetrahedral and trigonal species. Under a high electric field, over‐ and under‐coordinated Ge and S defects, together with three‐membered rings, form an interconnected network associated with localized and extended ...
Andrey Tverjanovich, Jörg C. Neuefeind, Chris J. Benmore, Daniele Fontanari, Anton Sokolov, Maxim Khomenko, Shinji Kohara, Aleksei Bytchkov, Takeshi Usuki, Maria Bokova, Mohammad Kassem, Pascal Masselin, Mariana Milochova, Eugene Bychkov   +13 more
wiley   +1 more source

Nanoporous BNC network on Au(111) from a borazine-based arylalkyne.

Chem Commun (Camb)
Ibarra-Barreno CM, Crosta M, Deyerling J, van Hunnik AJ, Seufert K, Bonifazi D, Auwärter W, Rudolf P.   +7 more
europepmc   +1 more source

On-surface synthesis and interfacial charge redistribution of open-shell [3]triangulene-fused porphyrins on Au(111). [PDF]

Natl Sci Rev
Martínez García M, Xiang F, Ortega-Guerrero A, Kumar M, Bassi N, Pignedoli CA, Ruffieux P, Torres T, Jelínek P, Fasel R, Bottari G.   +10 more
europepmc   +1 more source