Synthesis of Spiropyrrolines <i>via</i> One-Pot Tf<sub>2</sub>O-Mediated Amide Activation/Formal [3 + 2]-Cycloaddition of α-Formylamino Ketones. [PDF]
Ho KT, Pierce JG.
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Mechanism Inversion in Visible Light-Induced Photoclick Reactions. [PDF]
Fu Y +9 more
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Profiling the proteome-wide selectivity of diverse electrophiles. [PDF]
Zanon PRA +14 more
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1,2-Dihydropyrimidine synthesis <i>via</i> titanium-mediated multicomponent coupling of alkynes, nitriles, and aldehydes. [PDF]
Dunscomb RJ +3 more
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Skeletal Editing: Ring Insertion for Direct Access to Heterocycles. [PDF]
Li X, Xu Z.
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Azirines. V. The Reaction of 2-Phenyl-3, 3-pentamethylene1-azirine with Acid Chlorides
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Recent trends for chemoselectivity modulation in one-pot organic transformations. [PDF]
Chaudhary HR, Patel DM.
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Characterization of Azirine and Its Structural Isomers
The Journal of Physical Chemistry A, 2018The structures and spectroscopic properties of azirine (C2H3N), a nitrogen-containing three-membered cyclic molecule, and its isomers were studied with state-of-the-art ab initio quantum chemical methods. Azirine is isomeric with methyl cyanide (CH3CN) and methyl isocyanide (CH3NC)-both observed in the star-forming regions of Sgr B2.
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Gold vs Light: Chemodivergent Reactivity of Diazoesters toward 2H-Azirine-2-carboxylic Acids.
Organic Letters, 2023An orthogonal reactivity of diazo compounds toward azirine-2-carboxylic acids, switching with the reaction conditions, is demonstrated. A gold-catalyzed reaction is N-selective and produces 1,3-oxazin-6-ones, whereas a blue light activation leads to O-H ...
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