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Mechanism Inversion in Visible Light-Induced Photoclick Reactions. [PDF]

open access: yesJ Am Chem Soc
Fu Y   +9 more
europepmc   +1 more source

Profiling the proteome-wide selectivity of diverse electrophiles. [PDF]

open access: yesNat Chem
Zanon PRA   +14 more
europepmc   +1 more source
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Characterization of Azirine and Its Structural Isomers

The Journal of Physical Chemistry A, 2018
The structures and spectroscopic properties of azirine (C2H3N), a nitrogen-containing three-membered cyclic molecule, and its isomers were studied with state-of-the-art ab initio quantum chemical methods. Azirine is isomeric with methyl cyanide (CH3CN) and methyl isocyanide (CH3NC)-both observed in the star-forming regions of Sgr B2.
Claire E. Dickerson   +2 more
openaire   +3 more sources

Gold vs Light: Chemodivergent Reactivity of Diazoesters toward 2H-Azirine-2-carboxylic Acids.

Organic Letters, 2023
An orthogonal reactivity of diazo compounds toward azirine-2-carboxylic acids, switching with the reaction conditions, is demonstrated. A gold-catalyzed reaction is N-selective and produces 1,3-oxazin-6-ones, whereas a blue light activation leads to O-H ...
Gleb D Titov   +6 more
semanticscholar   +1 more source

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