Results 51 to 60 of about 30,490 (251)

Bistability loss as key feature in azobenzene (non-)switching on metal surfaces

open access: yes, 2012
Coinage metal adsorbed azobenzene is investigated as prototypical molecular switch. It is shown that switching capabilities are not just lost due to excited state quenching, but already due to changes in the ground state energetics.
Maurer, Reinhard J., Reuter, Karsten
core   +1 more source

Assessing computationally efficient isomerization dynamics: Delta-SCF density-functional theory study of azobenzene molecular switching [PDF]

open access: yes, 2011
We present a detailed comparison of the S0, S1 (n -> \pi*) and S2 (\pi -> \pi*) potential energy surfaces (PESs) of the prototypical molecular switch azobenzene as obtained by Delta-self-consistent-field (Delta-SCF) Density-Functional Theory (DFT), time ...
Maurer, Reinhard J., Reuter, Karsten
core   +3 more sources

Deciphering Small Molecule Diffusion Parameters Across Light Responsive Polymersome Membranes

open access: yesAdvanced Functional Materials, EarlyView.
Light‐responsive polymersomes bearing donor–acceptor Stenhouse adducts (DASAs) enable programmable control over small‐molecule transport across synthetic membranes. By systematically varying DASA density, an optimal functionalization regime is identified that maximizes light‐gated permeability.
Farzina Matubbar   +7 more
wiley   +1 more source

Photo-Controlled Adhesives Based on Photoinduced Solid-to-Liquid Transition of an Azobenzene Compound

open access: yesOrganic Materials, 2020
The development of photo-controlled adhesives can overcome the problems associated with daily lives and industrial applications. Adhesion is a multidiscipline field of engineering, physics, and chemistry.
Bing Niu   +4 more
doaj   +1 more source

UV-isomerisation in nematic elastomers as a route to photo-mechanical transducer

open access: yes, 2002
The macroscopic shape of liquid crystalline elastomers strongly depends on the order parameter of the mesogenic groups. This order can be manipulated if photoisomerisable groups, e.g. containing N=N bonds, are introduced into the material.
Cviklinski, J.   +2 more
core   +1 more source

External Reflection From Two‐Photon Laser‐Printed Micromirrors Enables Photomechanical Actuation at a 90° Incident Angle

open access: yesAdvanced Functional Materials, EarlyView.
Light reflectance increases along incidence angle and transmittance significantly drops around 90‐degree incidence angle. Here, we report two‐photon laser printed micro mirrors that redirect the skimming light beam into normal light absorption. Using this technique, light‐driven micro walkers and grippers are demonstrated by using grazing incidence ...
Leilei Song, Jianfeng Yang, Hao Zeng
wiley   +1 more source

A tetra-ortho-Chlorinated Azobenzene Molecule for Visible-Light Photon Energy Conversion and Storage

open access: yesMolecules
The development of photoactive molecules for photothermal energy storage is a focus of research in solar energy utilization technology. Azobenzene photoswitch has emerged as a promising candidate for solar energy conversion and storage due to its unique ...
Shuxin Tang   +6 more
doaj   +1 more source

Synthesis and Conformation of Substituted Chiral Binaphthyl-Azobenzene Cyclic Dyads with Chiroptical Switching Capabilities

open access: yesMolecules, 2011
Optically active binaphthyl-azobenezene cyclic dyads were synthesized to develop a photochromic switching molecule. Azobenezene moieties were cis-trans isomerized by photoirradiation.
Masuki Kawamoto, Kazuto Takaishi
doaj   +1 more source

Artificial Intelligence as the Next Visionary in Liquid Crystal Research

open access: yesAdvanced Functional Materials, EarlyView.
The functions of AI in the research laboratory are becoming increasingly sophisticated, allowing the entire process of hypothesis formulation, material design, synthesis, experimental design, and reiterative testing to be automated. In our work, we conceive how the incorporation of AI in the laboratory environment will transform the role and ...
Mert O. Astam   +2 more
wiley   +1 more source

Photocontrolled DNA minor groove interactions of imidazole/pyrrole polyamides

open access: yesBeilstein Journal of Organic Chemistry, 2020
Azobenzenes are photoswitchable molecules capable of generating significant structural changes upon E-to-Z photoisomerization in peptides or small molecules, thereby controlling geometry and functionality.
Sabrina Müller   +5 more
doaj   +1 more source

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