Results 61 to 70 of about 20,971 (273)

Synthesis and Conformation of Substituted Chiral Binaphthyl-Azobenzene Cyclic Dyads with Chiroptical Switching Capabilities

open access: yesMolecules, 2011
Optically active binaphthyl-azobenezene cyclic dyads were synthesized to develop a photochromic switching molecule. Azobenezene moieties were cis-trans isomerized by photoirradiation.
Masuki Kawamoto, Kazuto Takaishi
doaj   +1 more source

Azobenzene‐Oxindole Photochromic Dyads

open access: yesAngewandte Chemie
Abstract Manipulation of molecular geometry using photoresponsive units is a powerful tool in supramolecular chemistry, smart materials, and photopharmacology. Current synthetic chemistry offers many responsive molecules that perform such a task.
Ovalle, Marco   +2 more
openaire   +3 more sources

Spatial Homeotropic and Planar Liquid Crystal Alignment Patterning

open access: yesAdvanced Materials Interfaces, EarlyView.
A voltage‐assisted two‐step photoalignment methodology achieves precise micro‐patterning of alternating planar and homeotropic liquid crystal domains. Applying an AC electric field during in situ laser illumination minimizes phase retardation, reducing the required exposure dose. This cooperative mechanism enables high‐resolution spatial patterning and
Mingye Li, Inge Nys, Jeroen Beeckman
wiley   +1 more source

Monitoring cis-to-trans isomerization of azobenzene using Brillouin microscopy

open access: yesJPhys Photonics
Brillouin spectroscopy is commonly used to study the acoustic properties of materials. Here we explored its feasibility in studying the photoinduced isomerization of azobenzene.
Zhe Wang   +5 more
doaj   +1 more source

3D‐Printed Actuator Powered by Liquid Crystal Elastomer Muscles at the Water–Air Interface

open access: yesAdvanced Materials Technologies, EarlyView.
Soft robots for unstructured environments require responsive, durable actuators. Liquid crystal elastomers (LCEs) provide large reversible deformations under thermal or optical stimuli. Direct ink writing enables fabrication of LCE actuators integrated with silicone, with mesogen chemistry and oligomers optimized for printable inks.
Cecilie Ryberg   +5 more
wiley   +1 more source

Photocontrolled DNA minor groove interactions of imidazole/pyrrole polyamides

open access: yesBeilstein Journal of Organic Chemistry, 2020
Azobenzenes are photoswitchable molecules capable of generating significant structural changes upon E-to-Z photoisomerization in peptides or small molecules, thereby controlling geometry and functionality.
Sabrina Müller   +5 more
doaj   +1 more source

Single‐Step Fabrication of Smart 3D Microstructures Exploiting Naphthopyrans as Photoinitiators and Photochromic Molecules

open access: yesAdvanced Optical Materials, EarlyView.
Naphthopyran–benzophenone compounds can act simultaneously as photoinitiators and photochromic molecules for two‐photon polymerization. Using a single‐step process, liquid photoresist is encapsulated within polymerized 3D microstructures, preserving reversible UV–vis photochromism after fabrication.
João P. Leote   +5 more
wiley   +1 more source

Azobenzene-Based Light-Responsive Hydrogel System

open access: yes, 2016
A deoxycholic acid-modified β-cyclodextrin derivative (2) and an azobenzene-branched poly(acrylic acid) copolymer (3) were prepared, and the association and dissociation of 2 with the trans/cis-azobenzene units in 3 were characterized by UV/vis ...
Yan-Li Zhao (752360)   +1 more
core   +2 more sources

Pointlike Material Accumulation and Displacement in Azopolymer Thin Films Driven by Spatial Light Modulation

open access: yesAdvanced Optical Materials, EarlyView.
A maskless, SLM‐driven approach enables the deterministic inscription of arbitrary topographical features in azopolymer films by mapping complex vectorial light fields onto local viscoplastic stress. This platform allows for the rapid generation and dynamic erasure of high‐aspect‐ratio micro‐spikes, offering a versatile tool for reconfigurable flat ...
Jonas Strobelt   +3 more
wiley   +1 more source

Hydrophilic Polymers in Gels and Solutions: Surface Properties and Structure [PDF]

open access: yes, 2008
Changes in the wetting properties of thin films of polyethyleneglycol (PEG) end-capped with fluoroalkyl groups are measured when the films are equilibrated at various relative humidity (RH).
Mackel, Michael John
core   +1 more source

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