Results 41 to 50 of about 4,123 (167)

Prediction of experimental excited‐state absorption spectra by using vibronic transition calculations: Its practical application to a π‐conjugated molecule

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Excited‐state absorption (ESA) spectra are notoriously hard to compute. We show that routine DFT and TDDFT vibronic transition calculations reproduce the vibronic band shapes and positions of azulene's experimental ESA spectrum, providing a practical route to assign ESA bands to specific electronic transitions and vibrational modes.
Joonyoung F. Joung, Sungnam Park
wiley   +1 more source

Azulene-Derived Fluorescent Probe for Bioimaging: Detection of Reactive Oxygen and Nitrogen Species by Two-Photon Microscopy

open access: yes, 2019
Two-photon fluorescence microscopy has become an indispensable technique for cellular imaging. Whereas most two-photon fluorescent probes rely on well-known fluorophores, here we report a new fluorophore for bioimaging, namely azulene.
Juyoung Yoon   +29 more
core   +1 more source

A Multi‐Stimuli Transformational Network of Benzil‐Based Pd(II) Assemblies

open access: yesAngewandte Chemie, Volume 138, Issue 36, 1 September 2026.
Incorporation of a flexible and chemically reactive benzil backbone into the ligand structure allows it to access multiple conformations, enabling the formation of diverse homo‐ and heteroleptic Pd(II) assemblies with different nuclearities and topologies.
Zhiwei Zeng   +5 more
wiley   +2 more sources

Calixazulenes: azulene-based calixarene analogues – an overview and recent supramolecular complexation studies

open access: yesBeilstein Journal of Organic Chemistry, 2018
Some of the least studied calixarenes are those that consist of azulene rings bridged by -CH2- groups. Since Lash and Colby’s discovery of a simple and convenient method for producing the parent all-hydrocarbon calix[4]azulene, there have been two other ...
Paris E. Georghiou   +6 more
doaj   +1 more source

Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

open access: yesMolecules, 2021
Isocyanoazulenes (CNAz) constitute a relatively new class of isocyanoarenes that offers rich structural and electronic diversification of the organic isocyanide ligand platform. This article considers a series of 2-isocyano-1,3-X2-azulene ligands (X = H,
Mason D. Hart   +7 more
doaj   +1 more source

Cyclization of a 1,8‐Diphenylanthracene by Scholl Reactions to Form Five‐ and Seven‐Membered Ring Embedded Polycyclic Aromatic Hydrocarbons

open access: yesChemistry – A European Journal, EarlyView.
Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki   +2 more
wiley   +1 more source

Crystal structure of diethyl 2-amino-6-[(thiophen-3-yl)ethynyl]azulene-1,3-dicarboxylate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C22H19NO4S, has an almost planar geometry supported by intramolecular N—H...O and C—H...O hydrogen bonds. The thiophene ring is inclined to the azulene ring by 4.85 (16)°, while the ethoxycarbonyl groups are inclined to the azulene ...
Sebastian Förster   +2 more
doaj   +1 more source

Halogenated Tryptophans Improve Integrin αVβ6 Affinity of Cyclic RGD Peptides and Provide Handles for Late‐Stage Derivatization

open access: yesChemistry – A European Journal, EarlyView.
Lighting up αVβ6: Halotryptophan engineering converts an RGD scaffold into a modular αVβ6 ligand platform, enabling picomolar affinity and late‐stage functionalization. The resulting probes combine high selectivity with fluorescence for FACS and tumor imaging.
Beate Nachtigall   +4 more
wiley   +1 more source

Conjugated Diphenylaniline-Azulene Co-Oligomers with Intense Absorption and Emission in the Visible Region

open access: yesMolecules
New conjugated 2,6-diphenylaniline-azulene co-oligomers of linear and branched structure were synthesized by the interaction of borylazulenes with diphenylaniline bromides under Suzuki–Miyaura cross-coupling conditions.
Nurlan Merkhatuly   +4 more
doaj   +1 more source

A Colorimetric Chemosensor Based on a Nozoe Azulene That Detects Fluoride in Aqueous/Alcoholic Media

open access: yesFrontiers in Chemistry, 2020
Colorimetry is an advantageous method for detecting fluoride in drinking water in a resource-limited context, e. g., in parts of the developing world where excess fluoride intake leads to harmful health effects.
Lloyd C. Murfin   +11 more
doaj   +1 more source

Home - About - Disclaimer - Privacy