Results 191 to 200 of about 395,014 (238)

COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption

open access: yesAdvanced Materials, EarlyView.
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas   +11 more
wiley   +1 more source

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

open access: yesAdvanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea   +9 more
wiley   +1 more source

High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza   +11 more
wiley   +1 more source

Toward Energy Efficient Electrochemical Valorization of Waste Nitrate and Sulfide

open access: yesAdvanced Materials, EarlyView.
This work introduces an integrated electrochemical strategy couples nitrate reduction with sulfide oxidation for energy‐efficient wastewater valorization. A Cu‐Co dual‑site catalyst, engineered for close proximity, promotes *NO2 relay and subsequently NH3 formation, enabling the system to operate at substantially reduced cell voltages and produce high ...
Bihao Hu   +5 more
wiley   +1 more source

High‐Performance Flexible Near‐Infrared Organic Light‐Emitting Diodes with a Heterogeneous Alloy Semitransparent Electrode

open access: yesAdvanced Materials, EarlyView.
This study presents a micro‐structured magnesium‐bismuth alloy electrode that enhances flexible NIR OLEDs. The electrode provides 40% broadband transmittance (400–1600 nm) and boosts light outcoupling efficiency (42.3%) and photoluminescence quantum yield (71.8%) through the Purcell effect in optical microcavities.
Mengxin Xu   +10 more
wiley   +1 more source

Engineering Bilayer Tandem Catalysts on Si‐Based Photocathodes for High‐performance CO2 Reduction to Produce Methane

open access: yesAdvanced Materials, EarlyView.
A Cu/Ag‐Cu bilayer tandem catalyst is designed for a pyramid‐structured p‐Si photocathode, creating multiple and functionally distinct interfaces tailored to specific reaction steps and intermediate stabilization. This Cu/Ag‐Cu‐decorated p‐Si photocathode exhibits both high photocurrent and good selectivity for photoelectrochemical CO2 reduction to CH4.
Hao Wu   +14 more
wiley   +1 more source

Liquid Metal Microrobots for Magnetically Guided Transvascular Navigation

open access: yesAdvanced Materials, EarlyView.
Liquid metal‐based microrobots combine magnetic steering, intrinsic X‐ray visibility and softness, to navigate blood vessels even against flow. Under clinically relevant magnetic fields, liquid metal microrobots roll along vessel walls, cross endothelial barriers, and accumulate in target tissues.
Xiaohui Ju   +7 more
wiley   +1 more source

Photoresponsive Adaptive Reconfiguration of Single‐Atom Interface With Intermittent Light and Soft Ionic Lattices

open access: yesAdvanced Materials, EarlyView.
We present a photoresponsive platform that integrates SACs with halide perovskite supports, turning perovskite ion mobility, typically a stability concern, into a functional mechanism for light‐regulated self‐repair and reversible atomic reconfiguration. Adaptive metal‐support interactions are established through bandgap‐funnel engineering and the soft
Li Yu   +10 more
wiley   +1 more source

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