Results 151 to 160 of about 3,258 (214)

Magnetic field‐assisted concentration swing adsorption for CO2 capture over Fe3O4/fibrous nanosilica‐PEI adsorbent

open access: yesAIChE Journal, EarlyView.
Abstract Magnetic field‐assisted concentration swing adsorption (CSA) provides an electrification‐compatible alternative to conventional temperature swing adsorption (TSA) by enabling rapid heating/cooling and energy‐efficient regeneration under near‐isothermal conditions, thereby eliminating the need for sensible heat input.
Xiaohao Jia, Fateme Rezaei
wiley   +1 more source

Spatially Coupled Cl2 Confinement and Activation at Curved Ni Single‐Atom Sites for Highly Reversible Li–Cl2 Batteries

open access: yesAngewandte Chemie, EarlyView.
A robust cathode featuring curvature‐engineered Ni single‐atoms anchored within hierarchical pores effectively confines Cl2 and accelerates Cl0/Cl−1 redox kinetics. This synergistic architecture unlocks the potential of Li‐Cl2 secondary batteries with an unprecedented 1×106 mAh g−1 cumulative capacity, all‐climate resilience (–40°C to + 70°C), and 7.65
Minggang Xie   +11 more
wiley   +2 more sources

Joule self‐heating enabled oxygen transport and coupled methane reactions in a La0.6Sr0.4Co0.2Fe0.8O3‐δ hollow fiber membrane reactor

open access: yesAIChE Journal, EarlyView.
Abstract Mixed‐conducting ceramic hollow fiber membranes are a versatile platform for oxygen separation, value‐added chemical production, and oxy‐combustion. Because oxygen permeation is thermally activated, these systems typically rely on bulky, energy‐intensive furnaces that suffer from low efficiency and large thermal inertia.
Gang Wang   +2 more
wiley   +1 more source

Degradable Alternating Copolymers With Strained Cyclobutane Backbones via Photocontrolled RAFT Polymerization

open access: yesAngewandte Chemie, EarlyView.
A photocontrolled RAFT strategy enables the alternating copolymerization of 1,3‐disubstituted bicyclo[1.1.0]butanes with electron‐deficient comonomers, affording well‐defined copolymers bearing strained cyclobutane backbones. A high degree of alternation, tunable molecular weights, and excellent end‐group fidelity are achieved through a CTA‐mediated ...
Xia Hu   +4 more
wiley   +2 more sources

Accelerating the Discovery of Proton Conducting Electrolytes via Machine Learning‐Enabled Literature Mining

open access: yesAdvanced Intelligent Discovery, EarlyView.
An end‐to‐end knowledge discovery framework is established to automate high‐precision property extraction from small, specialized literature corpora. Utilizing a domain‐specific bidirectional encoder representation from a transformer model and data augmentation, the system accurately extracts and structures electrolyte performance data, ultimately ...
Gaheun Shin   +4 more
wiley   +1 more source

Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries

open access: yesAngewandte Chemie, EarlyView.
Developing viable cathode materials for multivalent battery chemistries is challenging due to the intrinsic sluggish diffusion kinetics. A disordered rocksalt oxide host was found to “lock” the cycling of zinc ions from nonaqueous electrolyte. We unlock zinc ion diffusion in the disordered rocksalt by introduction of a percolating vacancy network ...
Zixuan Li   +10 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +1 more source
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Direct Amidation of Esters by Ball Milling**

Angewandte Chemie - International Edition, 2021
Abstract The direct mechanochemical amidation of esters by ball milling is described. The operationally simple procedure requires an ester, an amine, and substoichiometric KOtBu and was used to prepare a large and diverse library of 78 amide structures with modest to excellent efficiency. Heteroaromatic and heterocyclic components are
Jamie Leitch   +2 more
exaly   +3 more sources

Slurry density effects on ball milling in a laboratory ball mill

Powder Technology, 1989
Abstract The effect of slurry density on the dynamics and grinding behavior of a batch ball mill was studied using quartz as a test material. It was found that slurry density determined the distribution of solid charge in the mill, with migration of particles from the tumbling zone to the mill periphery as solid concentration was progressively ...
C. Tangsathitkulchai, L.G. Austin
openaire   +1 more source

Raman spectroscopy of ball-milled TiO2

Journal of Molecular Structure, 2001
The Raman spectroscopy is method to analyze different crystal structure of TiO2. We applied it in order to study structural changes during high-energy ball milling of TiO2 powder. TiO2 anatase (tetragonal structure, space group I4/amd = D4h19) was milled up to 10 hours using two different sets of vials and balls.
Furić, Krešimir   +3 more
openaire   +3 more sources

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