Results 191 to 200 of about 325,462 (312)

Universal Oxychlorination Strategy in Halide Solid Electrolytes for All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A WO2Cl2‐driven oxychlorination strategy enables bulk oxygen incorporation into close‐packed LixMCl6 (M = Zr, Y, Er, In) halide lattices. Oxygen is selectively anchored by W6+ as lattice‐integrated [WO2Cl4]2− units, regulating the anionic framework, diversifying Li coordination, and weakening Li–Cl interactions.
Jae‐Seung Kim   +13 more
wiley   +1 more source

Investigation Into the Electrochemical Performance of Micron‐ and Nanosized Tin in Diglyme and Carbonate Electrolytes in Sodium Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This study compares Sn particles of different sizes in NIBs using carbonate‐ and diglyme‐based electrolytes. Diglyme electrolytes enable stable cycling despite large volume changes, while carbonate electrolytes degrade rapidly, especially with nanoparticles.
Chinnasamy Murugesan   +4 more
wiley   +1 more source

Silicon‐Based Anodes for Sulfide Solid‐State Batteries: Failure Mechanisms and Multiscale Design Strategies

open access: yesAdvanced Energy Materials, EarlyView.
Silicon anodes in sulfide SSBs face coupled electrochemo‐mechanical failure by interface instability. This review examined recent advances and proposed mitigation strategies via material‐, electrode/interface‐, and cell‐level‐ engineering. We further evaluate scalable synthesis of sulfide SEs.
Murugesan Karuppaiah   +4 more
wiley   +1 more source

Sputtering Mechanism of an Unsintered Organic–Inorganic Sputtering Target for Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
An unsintered MAPbI3 sputtering target fabricated via a mechanochemical route enables large‐area vacuum deposition of perovskite absorber layers, while revealing an ion–photon coupled decomposition mechanism that governs target erosion and film composition under RF plasma exposure.
Doha Lim   +9 more
wiley   +1 more source

Mechanisms of Alkali Ionic Transport in Amorphous Oxyhalides Solid State Conductors

open access: yesAdvanced Energy Materials, EarlyView.
Large‐scale machine learning‐based molecular dynamics simulations are used to investigate isovalent amorphous oxyhalides, revealing a remarkable chemically independent ionic conductivity. A rigorous analysis of alkali residence times across different metal–anion environments identifies divalent anions as key diffusion bottlenecks.
Luca Binci   +3 more
wiley   +1 more source

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