Mechanochemical S<sub>N</sub>Ar on Phthalonitriles: Distinct Reactivity and Selectivity in One-Pot Synthesis for Greener Phthalocyanines. [PDF]
Mechanochemical nucleophilic aromatic substitution enables efficient, reproducible functionalization of phthalonitriles under minimal solvent conditions with high versatility. Integrating this process with solid‐state cyclotetramerization affords metalated and metal‐free phthalocyanines in a streamlined sustainable one‐pot workflow.
Rodriguez-Perez O +3 more
europepmc +2 more sources
Mechanochemistry: Fundamental Principles and Applications
Mechanochemistry is an emerging research field at the interface of physics, mechanics, materials science, and chemistry. Complementary to traditional activation methods in chemistry, such as heat, electricity, and light, mechanochemistry focuses on the ...
Yi Cao, Hai Lei
exaly +2 more sources
Mechanochemistry in Europe: where we come from and where we are now [version 1; peer review: 2 approved] [PDF]
Mechanochemistry is several thousand years old, but it has been overlooked in favour of solution-based chemistry for long time and its methods have only recently emerged as a key technology for advancing green and sustainable chemistry, offering a ...
Juan José Sáenz de la Torre +3 more
doaj +2 more sources
Development of composite electrode materials based on nickel oxide for additive manufacturing of fuel cells [PDF]
In this work, a new composition of a paste based on nanosized nickel oxide (NiO) for jet-based 3D printing has been developed and investigated. The optimal parameters of anode paste with necessary viscosity and NiO loading have been found for printing by
Bagishev Artem +6 more
doaj +1 more source
Features of the formation of conductive films during thermal and laser sintering of silver nanoparticles stabilized by an ethoxylated carboxylic acid [PDF]
Silver nanoparticles (Ag NPs) of ~ 6 nm in size were synthesized by the reduction of silver 2-[2-(2-methoxyethoxy)ethoxy]acetate by benzyl alcohol acting both as the solvent and as the reducer.
Titkov Alexander I. +6 more
doaj +1 more source
Сocrystals of betulin with suberic acid: mechanochemical synthesis and thermal behavior [PDF]
In this work, the cocrystals of betulin with suberic acid were prepared by liquid-assisted grinding method using solvents of different polarity. The formation of cocrystals was confirmed by means of powder X-ray diffraction, IR spectroscopy and thermal ...
Mikhailovskaya Anastasiya +4 more
doaj +1 more source
Mechanochemistry and oleochemistry and their combination have been known for centuries. Nevertheless, bioeconomy and circular economy concepts is much more recent and has motivated a regain of interest of dedicated research to improve alternative ...
Christophe Len +5 more
doaj +1 more source
The investigation of molecular crystals at high pressure is a sought-after trend in crystallography, pharmaceutics, solid state chemistry, and materials sciences.
Valeriya Yu. Smirnova +2 more
doaj +1 more source
Polymer and small molecule mechanochemistry: closer than ever
The formation and scission of chemical bonds facilitated by mechanical force (mechanochemistry) can be accomplished through various experimental strategies.
José G. Hernández
doaj +1 more source
Hydrolytic method for processing bismuth to obtain compounds [PDF]
The hydrolytic processing of metallic bismuth to obtain compounds was investigated by methods of chemical, X-ray diffraction analyses, thermogravimetric analyzes, as well as electron microscopy.
Daminov Artem S. +3 more
doaj +1 more source

