Experimentally realized mechanochemistry distinct from force-accelerated scission of loaded bonds [PDF]
, 2017 Stretching polymer chains accelerates dissociation of a variety of internal covalent bonds, to an extent that correlates well with the force experienced by the scissile bond.
Akbulatov, Sergey +5 more
core +1 more source
Solvent-free copper-catalyzed click chemistry for the synthesis of novel N-heterocyclic hybrids based on quinolone and 1, 2, 3-triazole [PDF]
, 2017 Copper-catalyzed mechanochemical click reactions have been successfully implemented to provide novel 6-phenyl-2- (trifluoromethyl)quinolones with phenyl-1, 2, 3- triazole moiety at O-4 of quinolone core. Milling procedures utilizing CuI and brass milling
Cetina, Mario +8 more
core +6 more sources
Introductory lecture: Mechanochemistry, a versatile synthesis strategy for new materials. [PDF]
, 2014 Mechanochemistry deals with reactions induced by the input of mechanical energy - for example by impacts within a vibratory ball mill. The technique has a long history with significant contributions from Ostwald, Carey Lea and, notably, Faraday ...
Eddleston, Mark D, Jones, William
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Geophysical Monograph Series, Page 341-349., 2020 This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.
Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Sulgiye Park, Yu Lin, Wendy L. Mao
wiley +1 more source
Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity
Angewandte Chemie, EarlyView.This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte +2 more
wiley +2 more sources
Ceramics, 2022 An anode for solid oxide fuel cells (SOFCs) was fabricated using 3D inkjet printing and layer-by-layer laser treatment of compositions based on the NiO/YSZ system followed by thermal sintering.
Inna Malbakhova +5 more
doaj +1 more source
Theoretical studies of a hydrogen abstraction tool for nanotechnology [PDF]
, 1991 In the design of a nanoscale, site-specific hydrogen abstraction tool, the authors suggest the use of an alkynyl radical tip. Using ab initio quantum-chemistry techniques including electron correlation they model the abstraction of hydrogen from ...
Goddard, William A., III +3 more
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Angewandte Chemie, EarlyView.Anionic α‐silyl alkyl is one of the most used organometallic building blocks and funtional groups. Traditionally, the C─Si bond in these complexes is considered as inert. In this work, we report a series of reactions between mononuclear organo‐lithium and ‐sodium complexes with CO, CO2, or heteroallenes.
Xiao Yang +8 more
wiley +2 more sources
Mechanochemistry as an emerging tool for molecular synthesis: what can it offer? [PDF]
, 2018 Mechanochemistry is becoming more widespread as a technique for molecular synthesis with new mechanochemical reactions being discovered at increasing frequency.
Browne, Duncan, Cao, Qun, Howard, Joseph
core +3 more sources
Mechanochemical reactions and syntheses of oxides [PDF]
, 2013 Technological and scientific challenges coupled with environmental considerations have prompted a search for simple and energy-efficient syntheses and processing routes of materials. This tutorial review provides an overview of recent research efforts in
Becker, Klaus-Dieter +4 more
core +2 more sources