Results 61 to 70 of about 7,069 (224)

Copolymer of VDF/TFE as a Promising Polymer Additive for CsH2PO4-Based Composite Electrolytes

open access: yesMembranes, 2023
The composite polymer electrolytes (1-x)CsH2PO4-xF-2M (x = 0–0.3) have been first synthesized and their electrotransport, structural, and mechanical properties were investigated in detail by impedance, FTIR spectroscopy, electron microscopy, and X-ray ...
Yuri Kungurtsev   +2 more
doaj   +1 more source

The Mechanochemistry of Molecular Motors [PDF]

open access: yesBiophysical Journal, 2000
A theory of molecular motors is presented that explains how the energy released in single chemical reactions can generate mechanical motion and force. In the simplest case the fluctuating movements of a motor enzyme are well described by a diffusion process on a two-dimensional potential energy surface, where one dimension is a chemical reaction ...
Keller, David, Bustamante, Carlos
openaire   +2 more sources

High-Conductive CsH2PO4 Membranes with PVDF-Based Polymers Additives

open access: yesMembranes, 2023
The study is devoted to one of the important problems of hydrogen energy—the comparative analysis and creation of novel highly conductive and durable medium-temperature proton membranes based on cesium dihydrogen phosphate and fluoropolymers.
Irina Bagryantseva   +2 more
doaj   +1 more source

Activation of Metal Complexes With Ultrasound Waves for Targeted Anticancer Therapy

open access: yesAngewandte Chemie International Edition, EarlyView.
Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean   +3 more
wiley   +1 more source

Accelerating green heterocyclic synthesis: Convergence of AI, automation, and sustainable chemistry

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Green heterocyclic synthesis and data‐driven tools such as AI, high‐throughput experimentation, continuous flow, and self‐driving laboratories have developed largely in parallel. This review connects them and asks how green metrics such as E‐factor and PMI might serve as explicit optimization targets rather than post‐hoc measures, toward sustainable ...
Noor Aisyah Ahmad Shah   +8 more
wiley   +1 more source

Mild C─F Activation of Azido(per)Fluoroalkanes

open access: yesChemistry – A European Journal, EarlyView.
Mild and selective activation of C(sp3)–F bonds in azido(per)fluoroalkanes using thiolates was developed, leading to novel functionalized azides. The reaction is initiated by nucleophilic attack of the sulfur atom to the terminal nitrogen of the azido group, followed by fluoride ion elimination.
Olena Shaitanova   +7 more
wiley   +1 more source

Introducing RSC Mechanochemistry [PDF]

open access: yes
Co-Editors-in-Chief James Batteas and Tomislav Friščić introduce RSC ...
Friščić, Tomislav; id_orcid   +1 more
core   +1 more source

Tribochemical Surface Modification of Silicon

open access: yesChemistry – A European Journal, EarlyView.
Mechanical scribing activates silicon surfaces by generating reactive sites that spontaneously graft alcohol‐, thiol‐, and alkyne‐terminated molecules under ambient conditions. Within 10 s, high‐coverage, electroactive organic layers form without light, heat, or applied voltage, offering a rapid tribochemical route to functional silicon interfaces for ...
Abdulrahman O. Abdulrahman   +6 more
wiley   +1 more source

Mechanochemistry: A Force of Synthesis [PDF]

open access: yesACS Central Science, 2016
The past decade has seen a reawakening of solid-state approaches to chemical synthesis, driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, i.e., chemical transformations initiated or sustained by mechanical force, has been advancing particularly rapidly, from a laboratory curiosity to a widely applicable technique that not
Jean-Louis Do, Tomislav Friščić
openaire   +3 more sources

Sustainable Revival of Spent Lithium Iron Phosphate Cathodes in Li‐Ion Batteries: Recycling and Surface Engineering Approaches

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Schematic illustration of the lifecycle of LiFePO4 cathodes. Lithiation and delithiation reactions happen through its discharging and charging processes. Recycling pathways including hydrometallurgy, pyrometallurgy, and direct regeneration enable sustainable reuse of spent LFP materials. Surface modification approaches (carbon, polymer, and metal/metal
Yan He, Ruigang Wang
wiley   +1 more source

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