Results 181 to 190 of about 10,890,169 (287)

Force-Accelerated Autocatalysis in a Knoevenagel Condensation Reaction during Ball Milling. [PDF]

open access: yesJ Am Chem Soc
Floyd KR   +5 more
europepmc   +1 more source

Synergistic Optimization of Cathode Composite Architecture and Stack Pressure for High‐Performance All‐Solid‐State Chloride‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Composite cathode engineering and stack pressure co‐optimization enable a high‐performance all‐solid‐state chloride‐ion battery based on a VOCl/CsSn₀.₉In₀.₀₆₇Cl3/In architecture, delivering 169 mAh g−1 with 500‐cycle durability. Electrode‐resolved impedance tracking via distribution of relaxation times revealed progressive interphase and charge ...
Soutam Panja   +7 more
wiley   +1 more source

SOC Mismatch–Driven Inter‐Particle Synchronization via Internal Li‐Ion Transfer: An Unrecognized Electrode‐Emergent Degradation Pathway in Ni‐Rich Composite Cathodes

open access: yesAdvanced Energy Materials, EarlyView.
Composite cathode degradation is not merely the sum of its particles. Kinetically mismatched populations develop state‐of‐charge differences that drive spontaneous internal Li‐ion transfer; the accompanying transient currents accelerate surface degradation.
Seheon Oh   +5 more
wiley   +1 more source

MXene‐Derived Highly Oriented TiN Enables Ta3N5 Photoanodes for Transmission‐Mode Bias‐Free Solar Water Splitting

open access: yesAdvanced Energy Materials, EarlyView.
This work reports 2D MXene‐derived TiN thin films with (111)‐preferred orientation for transparent Ta3N5 photoanodes, demonstrating effective electron transfer behavior. All‐nitride electron‐collection architecture based on MXene‐derived TiN and n‐GaN resolves a long‐standing materials bottleneck between photocarrier transport and light transmission in
Jin Wook Yang   +10 more
wiley   +1 more source

Decoupling Thermodynamic and Kinetic Moisture Instability Reveals a Critical Humidity Threshold for Sodium Thiophosphate Solid Electrolyte

open access: yesAdvanced Energy Materials, EarlyView.
A quantitative exposure‐heat treatment framework identifies a critical humidity threshold (15%RH) and heat treatment temperature (80°C) that governs the recoverability of air‐exposed Na3PS4, revealing the decoupled thermodynamic and kinetic contributions to its moisture stability.
Boling Liu   +10 more
wiley   +1 more source

Mechanistic Origin of Capacity Limitation in Sidorenkite‐Type Na3‐xFe(PO4)(CO3) Carbonophosphate Cathodes for Na‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti   +7 more
wiley   +1 more source

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