Recent advances in TiO2 modification strategies: structure regulation and composite engineering for improved activity and functionality. TiO2 has emerged as a pivotal catalyst for enhancing MgH2, a high‐capacity solid‐state hydrogen storage material, owing to its structural versatility.
Xiaopeng Chu +10 more
wiley +1 more source
High‐loading tin single‐site catalysts (>7.5 wt.% Sn) are synthesized using a nitrogen‐enriched carbon scaffold and mechanochemically assisted pyrolysis to stabilize atomically dispersed Sn. The resulting Sn/N‐C‐M catalyst enables highly selective CO2‐to‐formate conversion (>90% FE across 50–500 mA cm−2) with long‐term durability and operando‐verified ...
Katharina Potemkin +12 more
wiley +2 more sources
Experimental Proof to Natural Hydrogen Generated Through Serpentinization of Olivine at Room Temperature and Ambient Pressure With Mechanochemistry. [PDF]
Ye J, Demirbas D, Felderhoff M.
europepmc +1 more source
In Vivo Nb4C3Tx MXene‐Assisted Photothermal Therapy of Melanoma in Mice
Nb4C3Tx MXene converts pulsed 1064 nm irradiation into localized heat, producing concentration‐ and time‐dependent melanoma cell killing in vitro and suppressing tumor growth in mice. Histology reveals extensive tumor damage, macrophage‐associated material clearance, and no detectable persistent deposits in examined visceral organs, supporting Nb4C3Tx ...
Anton Roshchupkin +22 more
wiley +1 more source
Radical, Not Ionic: The Mechanochemical Zincke Nitration of Phenols
Mechanochemistry recasts the classical Zincke nitration as an open‐shell process. Liquid‐assisted vibrational milling of phenols with in situ HNO2 delivers direct and ipso nitration across 50 substrates, while atmosphere, NOx‐transfer, EPR and DFT evidence expose a phenoxyl‐radical/NO2 manifold underlying this historically ionic transformation ...
Roberto Scipione +7 more
wiley +2 more sources
Preparation and characterization of O/W Nanoemulsions stabilized by covalent complex of ball-milled soy protein isolate and Chlorogenic acid. [PDF]
Zhang S, Jing Y, Yang X, Li L.
europepmc +1 more source
Ultrasonic and mechanochemical strategies for the synthesis of oxindole scaffolds mediated by hypervalent iodine(iii) reagents. [PDF]
Sivaraj N, Singh FV.
europepmc +1 more source
Mechanophotochemistry: Lighting up EDA Complexes in the Solid State
Examples of mechanophotochemical EDA complex‐mediated radical reactions, including a Giese reaction, a C─S cross‐coupling reaction, a phosphorylation reaction, and a sulfonylation reaction are shown to rapidly proceed in air using visible light excitation.
Aniket Kumar Srivastawa +1 more
wiley +2 more sources
Nano-NiFe<sub>2</sub>O<sub>4</sub> as a versatile and recyclable catalyst: an efficient protocol for the synthesis of aryl-1,2,4-triazolidine-3-thiones under ball milling conditions. [PDF]
Ledade PV +8 more
europepmc +1 more source
Magnesium‐Retention Assisted Synthesis of High‐Performance Zintl Thermoelectrics
Mg volatilization and chemical instability during high‐temperature synthesis hinder the scalable fabrication of Mg‐based thermoelectrics. Here, a magnesium‐retention assisted synthesis (MRAS) strategy stabilizes Mg using a sacrificial Mg reservoir and an inert‐gas‐regulated melting environment.
Boxuan Hu +9 more
wiley +2 more sources

