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Sur le Polymorphisme du barbital et le systeme eau-barbital
Journal of Thermal Analysis, 1987The crystal structures of three forms (I, II and IV) of barbital are well known. The DTA curve of barbital I is marked by only one endotherm, at 186°, which is the melting point of this crystalline form. For barbital II, the DTA curve shows a first endotherm at 160°, which indicates the transition point II ⇌ I, and then an endotherm at 186° for the ...
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SummaryThe effects of crystalline environment on radiation-induced free radicals in a model system of pyrimidines (barbital I, II, IV, and sodium barbital) were investigated. The characteristics of the stable room-temperature radical were determined by e.s.r. spectroscopy. Single-crystal studies were performed on barbital I and IV.
R A, Haak, B W, Benson
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