Results 191 to 200 of about 322,175 (261)

Selective Hydrodemethylation of Methylalkylbenzenes on Potassium Hydride

open access: yesAngewandte Chemie, EarlyView.
Selective catalytic hydrodealkylation of methylalkylbenzenes on carbon‐supported potassium hydride is reported. The reaction exhibits a reactivity trend of 1° ∼ 2° ∼ 3° < CH3, which is opposite to traditional dealkylation and hydrodealkylation. DFT calculations on the (001) facet of KH with ortho‐ethyltoluene suggest that selectivity is controlled by ...
Puyang Tian   +5 more
wiley   +2 more sources

Individualized Treatment in Distal and Medium Vessel Occlusion Stroke Using a Validated Explainable Counterfactual Treatment Estimation Model

open access: yesAnnals of Neurology, EarlyView.
Objective The optimal treatment for distal medium vessel occlusion (DMVO) stroke remains uncertain, and evidence comparing endovascular therapy (EVT) with medical management (MM) is limited. We aimed to develop and validate a predictive modeling tool to assess individual treatment benefit in DMVO stroke using explainable counterfactual treatment ...
Mohamed F. Doheim   +14 more
wiley   +1 more source

Dynamic Confinement Approach for High Metal Loading Single‐Atom Catalysts Based on Covalent Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
We introduced a new synthetic strategy for the preparation of high metal loading crystalline single‐atom catalysts based on covalent organic frameworks with atomically distributed Pd ions and metal contents of up to 22.2 wt%. Theoretical simulations reveal that the crystalline framework dynamically confines Pd atoms between different binding sites ...
Kyung Seob Song   +11 more
wiley   +2 more sources

Cortical asymmetry in autosomal dominant Alzheimer's disease progression. [PDF]

open access: yesBrain Commun
Pérez-Millan A   +28 more
europepmc   +1 more source

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