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Thermochemistry of some barium compounds
Journal of Chemical Thermodynamics, 2002Abstract The molar enthalpies of reaction of metallic barium with 0.047 mol·dm−3 HClO4 as well as the molar enthalpies of dissolution of BaCl2 in 1.01 mol·dm−3 HCl and in water have been measured at T=298.15 K in a sealed swinging calorimeter with an isothermal jacket.
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Selective Propargylation of Azo Compounds with Barium Reagents
Synlett, 2010A Barbier-type propargylation of azo compounds with γ-trialkylsilylated propargylic bromides has been achieved using reactive barium as a low-valent metal in THF. Corresponding propargylated hydrazines (α-adducts) were exclusively formed not only from azobenzenes (diaryldiazenes) but also from dialkyl azodicarboxylates.
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Selective Propargylation of Carbonyl Compounds and Imines with Barium Reagents
Chemistry - an Asian Journal, 2008AbstractA Barbier‐type regioselective propargylation of aldehydes and ketones with (3‐bromobut‐1‐ynyl)trimethylsilane has been achieved using reactive barium as a low‐valent metal in THF. Especially in the case of ketones, the corresponding homopropargylic alcohols form almost exclusively. In the reaction of α,β‐unsaturated carbonyl compounds, only 1,2‐
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Local Environment of Yttrium in Y-Doped Barium Cerate Compounds
Chemistry of Materials, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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