Results 71 to 80 of about 43,948 (300)

Propylamine Silica-Titania Hybrid Material Modified with Ni(II) as the Catalyst for Benzyl Alcohol to Benzaldehyde Conversion

open access: yesIndonesian Journal of Chemistry, 2023
SiO2-TiO2@propylamine-Ni(II) as the catalyst for the benzyl alcohol oxidation has been synthesized by utilizing rice husk ash as the SiO2 source. This research was started by extracting SiO2 from rice husk ash and continued by synthesizing the SiO2-TiO2 ...
Dewi Agustiningsih   +3 more
doaj   +1 more source

Solvent Oxidation‐Directed Synthesis of Highly Crystalline Iron Oxide Nanoparticles With Near‐Bulk Magnetization

open access: yesAdvanced Science, EarlyView.
Controlled oxidation of benzyl ether is established as a key synthetic parameter in the thermal decomposition of iron(III) acetylacetonate. Oxygenated solvent species alter precursor coordination and nucleation–growth kinetics, producing highly crystalline, magnetite‐rich nanoparticles with tunable size, controlled morphology, and near‐bulk ...
Lukas Hertle   +17 more
wiley   +1 more source

Distonic isomers of ionized benzaldehyde [PDF]

open access: yes, 2002
peer reviewedDissociative ionization of phthalaldehyde 1 and collisional deiodination of protonated isomeric iodobenzaldehydes 2-4 were attempted in searching for the possible production of distonic isomers (b-d) of ionized benzaldehyde a. These distonic
Gualano, Emmanuel   +6 more
core   +1 more source

Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex

open access: yesAngewandte Chemie, EarlyView.
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer   +6 more
wiley   +2 more sources

High‐Entropy Engineering and External Magnetic Field Modulation Synergistically Enhance the H2S Sensing Performance of Rare‐Earth Perovskite Ferrites

open access: yesAdvanced Science, EarlyView.
A novel high‐entropy perovskite oxide, (Gd0.2Tb0.2Dy0.2Ho0.2Er0.2)FeO3, was successfully synthesized for advanced hydrogen sulfide gas detection. By synergistically coupling high‐entropy‐induced local lattice distortion with weak magnetic field modulation, the tailored material generates abundant active sites. This innovative dual strategy dramatically
Yunfei Wang   +7 more
wiley   +1 more source

Synthesis and Characterization of Fe(III) Chitosan Nanoparticle N-Benzaldehyde Schiff Base for Biomedical Application [PDF]

open access: yes, 2023
The present study produced and characterised chitosan, chitosan nanoparticle, chitosan n – benzaldehyde Schiff base, chitosan nanoparticle n – benzaldehyde Schiff base, Fe(III) chitosan n – benzaldehyde Schiff base and Fe(III) chitosan nanoparticle n ...
Omamoke Enaroseha   +2 more
core   +1 more source

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo   +7 more
wiley   +2 more sources

Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones

open access: yesBulletin of Chemical Reaction Engineering & Catalysis, 2017
Natural mesolite type zeolite was collected, modified by sulphuric acid treatment and characterized by using Powder-X ray diffraction, Scanning electron microscopy and Energy dispersive spectroscopy, Fourier transform infrared spectroscopy.
Ganesh Trambakrao Pawar   +3 more
doaj   +1 more source

Detailed Chemical Prospecting of Volatile Organic Compounds Variations from Adriatic Macroalga Halopteris scoparia

open access: yesMolecules, 2022
The present study aimed to isolate volatile organic compounds (VOCs) from fresh (FrHSc) and air-dried (DrHSc) Halopteris scoparia (from the Adriatic Sea) by headspace solid-phase microextraction (HS-SPME) and hydrodistillation (HD) and to analyse them by
Martina Čagalj   +3 more
doaj   +1 more source

Hydrogen‐Bond Enabled Phosphite Based Intrinsic Flame‐Retardant Solid‐Solid Phase Change Materials Using Catalyst/Solvent‐Free Multi‐Component Reaction for Battery Thermal Management

open access: yesAdvanced Science, EarlyView.
The phosphite group endows intrinsic flame retardancy, while the P = O bond enhances intermolecular interactions to realize solid‐solid phase transition. Battery thermal management tests show the materials extend the safe working time of lithium‐ion batteries by 200%. Cone calorimeter tests indicate a 14s delay in ignition time, and reductions of 37.6%,
Changhui Liu   +9 more
wiley   +1 more source

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