Results 111 to 120 of about 50,349 (282)
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen +9 more
wiley +1 more source
The anionic 5,10,15-tris(4-carboxyphenyl), 20-mono(2-nitrophenyl) porphyrin (1), 5,10(or 15)-bis(4-carboxyphenyl), 15(or 10),20-bis(2-nitrophenyl)porphyrin (2) and 5-mono(4-carboxyphenyl), 10,15,20-tris(2-nitrophenyl)porphyrin (3) were sinthesized ...
Schiavon Marco A. +5 more
doaj
Expedient Iodocyclization Approach Toward Polysubstituted 3H-Benzo[e]indoles [PDF]
A facile and expedient iodocyclization of 4-(2-prop-1-ynylphenyl)-1H-pyrroles towards the synthesis of polysubstituted 3H-benzo[e]indoles is reported.
Back, David F. +4 more
core +2 more sources
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
The Polymorphism of Model United Nations: Students’ Guide [PDF]
This guide serves as a comprehensive introduction to Model United Nations (MUN), an educational simulation designed to immerse students in the dynamics of international diplomacy and decision-making. MUN conferences allow participants to assume the roles
Maruthi, T. R., Shahbaz, Syed
core +1 more source
Three 2‐phosphinophenylaluminum dichloride complexes were synthesized and characterized as novel intramolecular FLPs. These FLP systems exhibit high Lewis acidity and effectively activate challenging substrates including aliphatic ketones, imines, and esters. DFT analysis revealed that strain release and Al–P dynamics govern their reactivity. Abstract (
Yoshihiro Nishimoto +2 more
wiley +1 more source
Synthesis and Antiviral Bioactivities of α-Aminophosphonates Containing Alkoxyethyl Moieties
A simple, efficient, and general method has been developed for the synthesis ofvarious α-aminophosphonate derivatives 4a-4l by treatment of substituted benzaldehydes andaniline with bis(2-methoxyethyl)- or bis(2-ethoxyethyl) phosphite under ...
Zhuo Chen +10 more
doaj +1 more source
A straightforward one‐step protocol enables the synthesis of bio‐based and biologically active isochromans through the Oxa‐Pictet cyclization involving diverse aldehydes, including vanillin in combination with lignin‐derivable homovanillyl alcohol, a prominent aromatic platform chemical obtainable via diol‐assisted fractionation of lignocellulose ...
Anjali Kottayi +6 more
wiley +1 more source
A mild and efficient Dakin reaction mediated by lipase
We have developed a novel lipase-mediated method to realize the Dakin reaction. A wide range of hydroxylated benzaldehydes could be oxidized with high yields (from 90% to 97%) under mild reaction conditions.
Zhi Wang +7 more
doaj +1 more source
Oxidative esterification of aldehydes with alcohols using imidazolium perrhenate
Four imidazolium perrhenates were synthesized, characterized and used as efficient catalysts for the oxidative esterification of benzaldehydes with alcohols.
Ruixia Xie +5 more
doaj +1 more source

