Results 131 to 140 of about 46,343 (254)
Sustainable Syntheses of p-Hydroxycinnamic-Based Macrobisphenols: Progress, Challenges, and Comparative Assessment of Yield and Sustainability. [PDF]
Flourat AL +8 more
europepmc +1 more source
PNN Acetate Ruthenium(II) Complexes as Active Catalysts for Fatty Ester Hydrogenation
The acetate PNN ruthenium complexes efficiently catalyze the hydrogenation of methyl decanoate (model for the FAMEs reduction) to 1‐decanol without solvents and under mild reaction conditions. Selective hydrogenation of long‐chain and aromatic methyl‐ and ethyl esters has been achieved with trans‐[Ru(η1‐OAc)2(PNNG)(PPh3)] at extremely high S/C (up to ...
Maurizio Ballico +6 more
wiley +1 more source
Curcumin, a natural polyphenol, enables a fully bio‐based and metal‐free photocatalytic system for the aerobic oxidation of aryl‐ and alkyl‐methanamines to imines under blue light. Using 2‐methyltetrahydrofuran (2‐MeTHF) as a renewable solvent and molecular oxygen as the sole oxidant, the protocol affords up to 98% yield.
Tommaso Castiglia +7 more
wiley +1 more source
Brønsted Acid-Catalyzed Multicomponent Phosphonylation/Cyclization Strategy for the Synthesis of Phosphinylated 2<i>H</i>‑Isoindoles. [PDF]
Yang N +7 more
europepmc +1 more source
A palladium‐catalyzed alkynylation of cinnamyl carbonates with terminal alkynes provides efficient and stereoretentive access to 1,4‐enynes, enabling the synthesis of challenging diarylalkenyl propargylic frameworks. A mild and efficient palladium‐catalyzed alkynylation of 3‐aryl, 3,3‐diaryl, and aliphatic allylic carbonates with terminal alkynes has ...
Yuri Gazzilli +7 more
wiley +1 more source
The Asymmetric Self‐Replicative Alkylation of N‐Arylaldimines Using Organolithium Reagents
Here, we report a new asymmetric autoinductive reaction; the addition of nBuLi to N‐arylaldimines to form chiral lithium amides. The reaction proceeds with full conversion and complete transfer of chirality, representing the first example of an asymmetric autoinductive reaction with organolithium reagents.
Anka Hagelschuer +2 more
wiley +1 more source
Radical Sampling Enabled Saturated N-Heterocycle Cyclization. [PDF]
Cai Q +6 more
europepmc +1 more source
N-Heterocyclic Carbene (NHC) Catalysis in Enzymatic Organic Synthesis. [PDF]
Chen X +9 more
europepmc +1 more source
Synthesis and Bioactivity Studies of Benzimidazole-Chalcone Hybrids. [PDF]
Makgoathana HD +4 more
europepmc +1 more source
ABSTRACT Rationale Bioactive (E)‐stilbenoids in vine extracts are prone to light‐induced transformation into the respective (Z)‐isomers and further degradation products, often resulting in a loss of bioactivity. We sought to study stilbenoid degradation beyond that of the well‐researched resveratrol due to the high diversity of stilbenoids in nature ...
Paul Besrukow +3 more
wiley +1 more source

