Results 61 to 70 of about 368,638 (159)

Marine Bromophenol Derivative 3,4-Dibromo-5-(2-bromo-3,4-dihydroxy-6-isopropoxymethyl benzyl)benzene-1,2-diol Protects Hepatocytes from Lipid-Induced Cell Damage and Insulin Resistance via PTP1B Inhibition

open access: yesMarine Drugs, 2015
3,4-Dibromo-5-(2-bromo-3,4-dihydroxy-6-isopropoxymethyl benzyl)benzene-1,2-diol (HPN) is a bromophenol derivative from the marine red alga Rhodomela confervoides.
Jiao Luo   +8 more
doaj   +1 more source

Studies Relevant to the Functional Model of Mo-Cu CODH: In Situ Reactions of Cu(I)-L Complexes with Mo(VI) and Synthesis of Stable Structurally Characterized Heterotetranuclear MoVI2CuI2 Complex

open access: yesMolecules, 2023
In this study, we report the synthesis, characterization, and reactions of Cu(I) complexes of the general form Cu(L)(LigH2) (LigH2 = xanthene-based heterodinucleating ligand (E)-3-(((5-(bis(pyridin-2-ylmethyl)amino)-2,7-di-tert-butyl-9,9-dimethyl-9H ...
Umesh I. Kaluarachchige Don   +3 more
doaj   +1 more source

Valorization of Textile Waste: Enzymatic Upcycling of Terephthalic Acid Toward a Sustainable PET Value Chain

open access: yesBiotechnology and Applied Biochemistry, EarlyView.
ABSTRACT The rapid expansion of the global textile industry, driven by the fast‐fashion paradigm, which is characterized by low‐cost, short‐lived garments made from inexpensive synthetic fibers, has intensified environmental pressures through increased waste generation, resource depletion, microplastic pollution, and greenhouse gas emissions ...
Fares Al‐Ostoot   +2 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Synthesis, isolation, identification and characterization of new process-related impurity in isoproterenol hydrochloride by HPLC, LC/ESI-MS and NMR

open access: yesJournal of Pharmaceutical Analysis, 2017
One unknown impurity (Imp-II) during the analysis of laboratory batches of isoproterenol hydrochloride was detected in the level ranging from 0.04% to 0.12% by high performance liquid chromatography with UV detection.
Neeraj Kumar   +4 more
doaj   +1 more source

Thermodynamic characterisation of triazol ylimino-DNA interaction by UV–Vis spectroscopy

open access: yesJournal of Photochemistry and Photobiology, 2020
To efficiently design improved therapeutic agent, study of molecule-DNA interaction is a crucial step. In our previous study, we investigated comprehensive mechanism of some 1,2,4 triazol-4-ylimino derivatives, and they exhibited excellent in vitro anti ...
Rafia Nimal, Afzal Shah, Muhammad Saddiq
doaj   +1 more source

Modulation of Epigenetic Control by Advanced Molecular Tweezers

open access: yesChemistry – A European Journal, EarlyView.
Tailored dimeric molecular tweezers recognize the DNA‐binding part of Histone H4 and interrupt the essential histone‐DNA interaction. ABSTRACT This work addresses the question if supramolecular systems can be tailored to interfere with posttranslational modifications (PTM) and epigenetics.
My‐Hue‐Le   +9 more
wiley   +1 more source

Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes

open access: yesChemistry – A European Journal, EarlyView.
Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley   +1 more source

Synthesis and characterization of polymer networks obtained by conventional radical and RAFT copolymerization processes in supercritical carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Conventional and RAFT dispersion copolymerizations of HEMA and EGDMA in supercritical CO2 are compared in terms of swelling index (crosslink density), morphology, particle size distribution, and modular differential scanning calorimetry. Abstract The syntheses of net‐poly((2‐hydroxyethylene methacrylate)‐co‐(ethylene glycol dimethacrylate ...
Patricia Pérez‐Salinas   +6 more
wiley   +1 more source

A Self‐Enhanced Tandem Catalytic System for Olefin‐to‐Diol Conversion Powered by Single‐Atom Fe Catalysts With In Situ Generated Acid

open access: yesEcoEnergy, EarlyView.
A single‐atom iron catalyst with well‐defined Fe–N4 sites enables a tandem epoxidation‐hydrolysis process for converting terminal olefins to 1,2‐diols. The in situ‐generated isobutyric acid drives the hydrolysis step, affording broad substrate scope and excellent recyclability.
Tao‐Tao Liu   +7 more
wiley   +1 more source

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