Results 151 to 160 of about 59,638 (262)

N–O Dual Functional Group Transposition via Energy Transfer Photocatalysis

open access: yesAdvanced Science, EarlyView.
N–O dual functional group transposition (dFGT) enabled by the photocatalytic energy transfer (EnT) has been developed. This methodology is applicable to both activated and unactivated alkyl derivatives for dFGT, and it also successfully extended to N–N dFGT, demonstrating its general applicability.
Lei Bao   +4 more
wiley   +1 more source

Covalently Integrated Selenoviologen–N‐Heterocyclic Carbene–Pt Nanoparticles for Visible‐Light‐Driven Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
A covalently integrated single‐component photocatalyst is constructed by anchoring selenoviologen to platinum nanoparticles via robust N‐heterocyclic carbene ligands. The resulting Pt─C covalent bonds function dually as protective structural scaffolds and direct channels for ultrafast intramolecular electron transfer This precise interfacial ...
Wenxi He   +8 more
wiley   +1 more source

Revisiting Aromaticity and Chemical Bonding of Fluorinated Benzene Derivatives. [PDF]

open access: yesChemistryOpen, 2015
Torres-Vega JJ   +6 more
europepmc   +1 more source

Metal‐Half‐Salen Chemistry for One‐Pot Mineralization on Hydrophobic Polymer Membranes

open access: yesAdvanced Science, EarlyView.
Here we report a versatile one‐pot synthetic strategy for organic–inorganic composite membranes, which leverages a metal half‐Salen system to precisely govern the competing kinetics of coordination and hydrolysis. In contrast to conventional two‐step metal‐phenol chemistries, our integrated approach substantially simplifies the fabrication process ...
Rou‐Ming Wen   +8 more
wiley   +1 more source

Streamlined synthesis of functionalized dibenzo[<i>a</i>,<i>e</i>]pentalenes through potassium-mediated cyclization and late-stage thianthrenation. [PDF]

open access: yesRSC Adv
Bogner MM   +9 more
europepmc   +1 more source

Metal Active‐Site Exposure via Ligand Engineering Boosts CO2‐to‐Ethylene Conversion on Cu18 Nanoclusters

open access: yesAdvanced Science, EarlyView.
Through quantitative ligand stripping of [Cu18H17(PR3)10]+ nanoclusters via intramolecular interaction modulation, selectivity for CO2 electroreduction to C2H4 is significantly enhanced. The weakly coordinating ligand triggers dual‐ligand stripping (FEC2H4 = 70.59%), whereas the strongly coordinating ligand results in single‐ligand retention (FEC2H4 ...
Ziqi Chen   +8 more
wiley   +1 more source

A Covalent Organic Framework With Staggered Topology for Mimetic Transmembrane Transport of Hydrated Ions

open access: yesAdvanced Science, EarlyView.
Inspired by biological ion channels, an AB‐staggered β‐ketoenamine‐linked COF enables rapid hydrated‐ion transport through a biomimetic dehydration‐compensation mechanism, where carbonyl‐rich convergent channels partially offset ion dehydration energy. As aqueous Zn battery separators, the COF membranes suppress parasitic reactions and dendrite growth,
Xuan Li   +8 more
wiley   +1 more source

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