N–O Dual Functional Group Transposition via Energy Transfer Photocatalysis
N–O dual functional group transposition (dFGT) enabled by the photocatalytic energy transfer (EnT) has been developed. This methodology is applicable to both activated and unactivated alkyl derivatives for dFGT, and it also successfully extended to N–N dFGT, demonstrating its general applicability.
Lei Bao +4 more
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Design, Synthesis of Novel Quinazolinone Derivatives and Evaluation of EGFR Kinase Inhibition Activity via In Vitro and In Silico Studies. [PDF]
Kaya AZ +3 more
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A covalently integrated single‐component photocatalyst is constructed by anchoring selenoviologen to platinum nanoparticles via robust N‐heterocyclic carbene ligands. The resulting Pt─C covalent bonds function dually as protective structural scaffolds and direct channels for ultrafast intramolecular electron transfer This precise interfacial ...
Wenxi He +8 more
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Lucigenin: a strongly oxidizing dicationic photocatalyst for the direct azolation of arenes. [PDF]
Matei A +4 more
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Revisiting Aromaticity and Chemical Bonding of Fluorinated Benzene Derivatives. [PDF]
Torres-Vega JJ +6 more
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Metal‐Half‐Salen Chemistry for One‐Pot Mineralization on Hydrophobic Polymer Membranes
Here we report a versatile one‐pot synthetic strategy for organic–inorganic composite membranes, which leverages a metal half‐Salen system to precisely govern the competing kinetics of coordination and hydrolysis. In contrast to conventional two‐step metal‐phenol chemistries, our integrated approach substantially simplifies the fabrication process ...
Rou‐Ming Wen +8 more
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Streamlined synthesis of functionalized dibenzo[<i>a</i>,<i>e</i>]pentalenes through potassium-mediated cyclization and late-stage thianthrenation. [PDF]
Bogner MM +9 more
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Through quantitative ligand stripping of [Cu18H17(PR3)10]+ nanoclusters via intramolecular interaction modulation, selectivity for CO2 electroreduction to C2H4 is significantly enhanced. The weakly coordinating ligand triggers dual‐ligand stripping (FEC2H4 = 70.59%), whereas the strongly coordinating ligand results in single‐ligand retention (FEC2H4 ...
Ziqi Chen +8 more
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Study of Vibronic and Cationic Features of p-Diethoxybenzene via REMPI, Hole-Burning, and MATI Spectroscopy. [PDF]
Qin X, Zhao Y, Ji Z, Li C, Jia S.
europepmc +1 more source
Inspired by biological ion channels, an AB‐staggered β‐ketoenamine‐linked COF enables rapid hydrated‐ion transport through a biomimetic dehydration‐compensation mechanism, where carbonyl‐rich convergent channels partially offset ion dehydration energy. As aqueous Zn battery separators, the COF membranes suppress parasitic reactions and dendrite growth,
Xuan Li +8 more
wiley +1 more source

