Anticancer and Antimicrobial Activities of New Cobalt and Zinc Complex-Derived Benzimidazole Containing Nitro or Methyl Groups. [PDF]
ACS OmegaYilmaz O +4 more
europepmc +1 more source
Topology‐Dependent Coke Formation in the Catalytic Pyrolysis of Phenol Over HFAU and HZSM‐5 Zeolites
Angewandte Chemie, EarlyView.The coke formation and speciation during the catalytic pyrolysis of lignin over different zeolite topologies were studied with a combination of operando EPR spectroscopy and ex situ pulsed techniques aided with DFT calculations. Operando EPR data showed that the coke formation in HFAU is fast compared to HZSM‐5.
Jörg W. A. Fischer +6 more
wiley +1 more source
Triggering and Preventing Cyclization of o-Amino-Guanidinobenzenes to 2-Amino-Benzimidazoles. [PDF]
ChemistryHenel CLM +5 more
europepmc +1 more source
Angewandte Chemie, EarlyView.A novel molecular design strategy is employed to modify the D–A type SAM using an alkyne linker. Incorporation of the alkyne linker enhanced π‐electron delocalization, facilitating more efficient hole transfer, and strengthened interfacial bonding, thereby improving device stability. As a result, the perovskite solar cells achieved an impressive PCE of
Ziyang Xia +8 more
wiley +1 more source
Medicinal attributes of nitrogen heterocycles directing aldose reductase selectivity and potency. [PDF]
RSC Med ChemKumari A +5 more
europepmc +1 more source
Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity
Angewandte Chemie, EarlyView.This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte +2 more
wiley +1 more source
Influence of intramolecular interactions and transition state energetics on the strain-promoted azide-alkyne cycloaddition of 2-aminobenzenesulfonamide-containing cyclononynes. [PDF]
RSC AdvNakahara K, Kaneda K.
europepmc +1 more source
Stereoselective Biotransformation: Transfer of Learning to Advance Drug Metabolism and Biocatalysis
Angewandte Chemie, EarlyView.Understanding stereoselective biotransformations has implications for predicting drug disposition and response and may also inspire novel biocatalytic and biomimetic strategies to address challenges in metabolite and API synthesis. ABSTRACT Chirality is an important determinant of drug action, as enantiomers can exhibit markedly different ...
Grace A. Okunlola, Godwin A. Aleku
wiley +1 more source
A facile and practical method for the synthesis of <i>trans</i>-(±)-taxifolin and its derivatives via Darzens reaction. [PDF]
Beilstein J Org ChemPeng B +6 more
europepmc +1 more source
Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes
Angewandte Chemie, EarlyView.Formation of radicals in nonplanar hydrocarbons through thermally induced dehydrogenation leads to molecular transformation via intramolecular radical‐based cyclization and dimerization, leading to formation of nonbenzenoid nanographenes. ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling ...
Daniel Rothhardt +8 more
wiley +1 more source