Results 151 to 160 of about 33,099 (286)

Peripherally Fluorinated Tetraphenylethene: New Electron Extraction Interlayers for n‐i‐p Perovskite Solar Cells

Advanced Energy Materials, EarlyView.
Fluorinated tetraphenylethene (TPE) derivatives were developed as interfacial layers for perovskite solar cells. The optimized TFP‐TPE enhances interfacial compatibility, suppresses molecular aggregation, and improves charge extraction. Devices incorporating TFP‐TPE achieved a record efficiency of 25.29% and outstanding stability under humidity and ...
Xiao‐Xin Gao, Ezhumalai Yamuna, Liang‐Wei Lin, Roland C. Turnell‐Ritson, Shuqing Song, Wen Luo, Chenxu Zhao, Shao‐Huan Hong, Cheng‐Liang Liu, Shiyu Xing, Jun Shao, Paul J. Dyson, Ming‐Chou Chen, Mohammad Khaja Nazeeruddin   +13 more
wiley   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

Angewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa, Sophia Belrhomari, Ana McGinley, Clevin Anto Liju, Manting Mu, Max García‐Melchor, Eva Hevia   +6 more
wiley   +2 more sources

Cyclacene Stability: The Interplay of Strain, Aromaticity and Force Coupling. [PDF]

J Comput Chem
Somani A, Gupta D, Grunenberg J, Bettinger HF.   +3 more
europepmc   +1 more source

Deciphering Intricacies in Directional CO2 Conversion From Electrolysis to CO2 Batteries

Advanced Energy Materials, EarlyView.
This review will delve into the inherent connections and distinctions of CO2‐directed conversion in ECO2RR and CO2 batteries, in terms of product types, catalyst selection, catalytic mechanisms, and electrochemical performances, while proposing a benchmarking framework for the evaluation of CO2 batteries and innovative CO2 battery configurations for ...
Changfan Xu, Huaping Zhao, Lizhuang Chen, Weidong Shi, Guosheng Shao, Yong Lei   +5 more
wiley   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

Angewandte Chemie, EarlyView.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis, Matteo Damian, Francesco G. Mutti   +2 more
wiley   +2 more sources

Novel ^iPrRu-MACHO Salts: Synthesis and Catalytic Applications With Diverse H-Trans Ligands. [PDF]

ChemSusChem
Tran TA, Nori V, Nikol AT, Schoeler A, Nielsen MT, Jørgensen MSB, Kubus M, Larsen RW, Nielsen M.   +8 more
europepmc   +1 more source

Molecular Design and Interfacial Functions of Self‐Assembled Monolayers for Perovskite and Tandem Solar Cells

Advanced Energy Materials, EarlyView.
We identify two decisive levers for SAM interfaces: molecular design (carboxylic acid‐based, phosphonic acid, other anchoring chemistries, and polymeric SAMs) and mixing routes (co‐assembly, in situ assembly, pre‐ and post‐treatment). Coordinated tuning of headgroups and assembly pathways optimises energy alignment and film formation, suppresses ...
Jiaxu Zhang, Bochun Kang, Feng Yan
wiley   +1 more source

Solvent-Free Hydrogenation and Dehydrogenation of Quinoline and Quinaldine for the LOHC Concept. [PDF]

ACS Omega
Aakko-Saksa PT, Mykkänen AM, Repo T.
europepmc   +1 more source

Interpretable Machine Learning for Solvent‐Dependent Carrier Mobility in Solution‐Processed Organic Thin Films

Advanced Intelligent Discovery, EarlyView.
This work establishes a correlation between solvent properties and the charge transport performance of solution‐processed organic thin films through interpretable machine learning. Strong dispersion interactions (δD), moderate hydrogen bonding (δH), closely matching and compatible with the solute (quadruple thiophene), and a small molar volume (MolVol)
Tianhao Tan, Lian Duan, Dong Wang
wiley   +1 more source

Donor–Acceptor Pentacene Analogues With Near‐Infrared Emission and Tunable Aromaticity

Angewandte Chemie, EarlyView.
Air‐ and photostable heterocyclic pentacene analogues with donor and acceptor groups flanking a para‐quinodimethane core exhibit large dipole moments, narrow bandgaps, reversible redox behavior, and NIR‐I to NIR‐II absorption and emission with pronounced solvatochromism.
Krzysztof Nowak, Olaf Morawski, Muhammad Yasir Mehboob, Maja Morawiak, Krzysztof Noworyta, Cina Foroutan‐Nejad, Marek Grzybowski   +6 more
wiley   +2 more sources