Results 21 to 30 of about 33,099 (286)

Benzene-1,2-diaminium bis(hydrogen phosphonate) [PDF]

open access: yesIUCrData, 2016
The asymmetric unit of the title molecular salt, C6H10N2 2+·2H2PO3 −, contains half of a benzene-1,2-diaminium cation and a phosphite anion, the complete cation being generated by a crystallographic mirror plane. In the crystal, N—H...O hydrogen bonds generate R 2 2(9) and R
Md. Zahid   +4 more
openaire   +2 more sources

Iridium complexes bearing a PNP ligand, favoring facile C(sp^3)–H bond cleavage [PDF]

open access: yes, 2011
Hydrogen iodide is lost upon reaction of PNP with IrI_3, where PNP = 2,6-bis-(di-t-butylphosphinomethyl)pyridine to give crystallographically characterized Ir(PNP)*(I)_2, which reacts with H_2 to give Ir(PNP)(H)(I)_2.
Goddard, William A., III   +4 more
core   +1 more source

On the Insignificance of Photochemical Hydrocarbon Aerosols in the Atmospheres of Close-in Extrasolar Giant Planets [PDF]

open access: yes, 2004
The close-in extrasolar giant planets (CEGPs) reside in irradiated environments much more intense than that of the giant planets in our solar system. The high UV irradiance strongly influences their photochemistry and the general current view believed ...
-T, Anthony Y.   +5 more
core   +3 more sources

Exploring Orthogonality between Halogen and Hydrogen Bonding Involving Benzene [PDF]

open access: yesMolecules, 2021
The concept of orthogonality between halogen and hydrogen bonding, brought out by Ho and coworkers some years ago, has become a widely accepted idea within the chemists’ community. While the original work was based on a common carbonyl oxygen as acceptor for both interactions, we explore here, by means of M06-2X, M11, ωB97X, and ωB97XD/aug-cc-PVTZ DFT ...
Forni A.   +4 more
openaire   +4 more sources

Green and selective hydrogenation of aromatic diamines over the nanosheet Ru/g-C3N4-H2 catalyst prepared by ultrasonic assisted impregnation-deposition method

open access: yesGreen Energy & Environment, 2022
In this study, nanosheet g-C3N4-H2 was prepared by thermal exfoliation of bulk g-C3N4 under hydrogen. A series of Ru/g-C3N4-H2 catalysts with Ru species supported on the nanosheet g-C3N4-H2 were synthesized via ultrasonic assisted impregnation-deposition
Huanhuan Yang   +7 more
doaj   +1 more source

Sulfur analysis of Bolu-Mengen lignite before and after microbiological treatment using reductive pyrolysis and gas chromatography/mass spectrometry [PDF]

open access: yes, 2005
Atmospheric pressure-temperature programmed reduction coupled with on-line mass spectrometry (AP-TPR/MS) is used for the first time on microbiologically treated coal samples as a technique to monitor the degree of desulfurization of the various sulfur ...
Bozdemir T.   +27 more
core   +1 more source

Supramolecular Cluster Catalysis: A Case Study of Benzene Hydrogenation

open access: yesCHIMIA, 2003
The hydrogenation of benzene to give cyclohexane, catalysed under biphasic conditions by the water-soluble trinuclear arene ruthenium cluster cations [H3Ru3(C6H6)(C6Me6)2(O)]+ (1), [H3Ru3(C6H5Me)(C6Me6)2(O)]+ (2), [H3Ru3(1,4-MeC6H4Pri)(C6Me6)2 ...
Bruno Therrien   +4 more
doaj   +1 more source

"Analysis of degree of benzene ring hydrogenation in hydrogenating styrene-conjugated diene block copolymer with proton nuclear magnetic resonance spectroscopy"

open access: yesHecheng xiangjiao gongye
The microstructure and composition of styrene-conjugated diene block copolymer and its hydrogenation product hydrogenated styrene-conjugated diene block copolymer (HSBC) were determined by nuclear magnetic resonance spectroscopy, degree of benzene ring ...
LI Fu-shi1,2, MO Xiao-jun1, PENG Hong-li1, YANG Fan1, LIANG Hong-wen1, JI Xiang-ling2
doaj   +1 more source

Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene

open access: yesNature Communications, 2016
Baird’s rules say that the first triplet state of benzene displays antiaromatic character. Here, the authors exploit this to show that aromatic molecules can undergo rapid transfer hydrogenation or silylations without the need for metal catalysts when ...
Raffaello Papadakis   +14 more
doaj   +1 more source

Preparation of Nickel/Active Carboncatalyst and its Utilization for Benzene Hydrogenation

open access: yesIndonesian Journal of Chemistry, 2010
The research on the preparation of nickel catalyst impregnated on active carbon by two methods has been carried out. The impregnation of Ni metal was done using nickel(II) chloride as a precursor.
Enggelena Septiawati   +2 more
doaj   +1 more source

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