Results 121 to 130 of about 51,375 (336)

Changing N^C^O to C^N^O Coordination in Cyclometalated Pt(II) and Pd(II) Complexes Modulates Stability and Emission Characteristics: Toward Brighter Versatility

open access: yesChemistry – A European Journal, EarlyView.
A new class of cyclometalated metal complexes with pincer luminophores (C^N^O and N^C^O) is reported. They unite high photoluminescence efficiencies in liquid solutions at r.t. with tunable colors across the visible spectrum and convenient synthetic accessibility.
Joschua Lüke   +4 more
wiley   +1 more source

Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models

open access: yesChemistry – A European Journal, EarlyView.
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen   +4 more
wiley   +1 more source

Crystal structure of catena-poly[[aquabis(4-cyanobenzoato-κO)copper(II)]-μ-N,N-diethylnicotinamide-κ2N1:O]

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The asymmetric unit of the title polymeric compound, [Cu(C8H4NO2)2(C10H14N2O)(H2O)]n, contains one CuII atom, one coordinating water molecule, two 4-cyanobenzoate (CB) ligands and one coordinating N,N-diethylnicotinamide (DENA) molecule.
Nurcan Akduran   +3 more
doaj   +1 more source

Redox‐Targeting Reactions of Viologen‐Based Shuttles and Polymers Translated From Nonaqueous to Aqueous Electrolyte

open access: yesChemistry – A European Journal, EarlyView.
. ABSTRACT Redox‐targeting flow batteries (RTFBs) present an attractive strategy for enhancing the energy density of conventional redox flow batteries (RFBs) by integrating heterogeneous energy storage materials as capacity boosters. However, nearly all RTFB systems have been developed with nonaqueous redox chemistries, while capacity boosters in ...
Yuxin Liu   +4 more
wiley   +1 more source

VOCs Adsorption and Exchange Properties in Bispidine‐Based Mn(II) 1D CPs Made of Orthogonally Oriented Linear Chains

open access: yesChemistry – A European Journal, EarlyView.
Combining the chiral bispidine ligand L1 with MnCl2 affords coordination polymers (CPs) with an unusual topology for this family of compounds, consisting of orthogonally packed ribbon‐like one‐dimensional (1D) chains. Their behavior was investigated through single‐crystal‐to‐single‐crystal exchange with aromatic volatile organic compounds (VOCs) and ...
Meriem Goudjil   +8 more
wiley   +1 more source

A novel approach to oxoisoaporphine alkaloids via regioselective metalation of alkoxy isoquinolines

open access: yesBeilstein Journal of Organic Chemistry, 2017
Oxoisoaporphine alkaloids are conveniently prepared via direct ring metalation of alkoxy-substituted isoquinolines at C-1, followed by reaction with iodine.
Benedikt C. Melzer, Franz Bracher
doaj   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque   +3 more
wiley   +1 more source

Selective Modification of the Product Profile of Biocatalytic Hydrolyzed PET via Product‐Specific Medium Engineering

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks   +8 more
wiley   +1 more source

Triterpene benzoates from the bark of Picramnia teapensis (Simaroubaceae)

open access: yesJournal of the Brazilian Chemical Society, 2001
Two new benzoic acid esters of triterpene alcohols [lup-20(29)-en-28-oic acid 3alpha,7beta-dibenzoate and 3alpha-hydroxy-lup-20(29)-en-28-oic acid 7beta-benzoate] were isolated from the stem bark of Picramnia teapensis Tul.
Rodríguez-Gamboa Tatiana   +10 more
doaj  

Visible light photoredox-catalyzed deoxygenation of alcohols

open access: yesBeilstein Journal of Organic Chemistry, 2014
Carbon–oxygen single bonds are ubiquitous in natural products whereas efficient methods for their reductive defunctionalization are rare. In this work an environmentally benign protocol for the activation of carbon–oxygen single bonds of alcohols towards
Daniel Rackl   +3 more
doaj   +1 more source

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