Results 121 to 130 of about 3,385 (223)

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Nephrotoxic Effects of Endocrine-Disrupting Chemicals: A Systematic Review. [PDF]

open access: yesCureus
Ahmed AE   +9 more
europepmc   +1 more source

Dilithium Enediamide Derived From 1,4‐Diaza‐1,3‐Diene: An Electron Reservoir Enabling Variable Reactivity Toward Carbonyl Compounds

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 21, 25 July 2026.
Upon reduction of 1,4‐diaza‐1,3‐diene 1 to the dilithium enediamide 2, the polarity of the C = N bonds is reversed ‐ a classic case of umpolung. This behavior is particularly evident in reactions of the dianion 2 with carbonyl compounds and also explains why 1,4‐diaza‐1,3‐diene ligands do not always act merely as spectator ligands. 1,4‐Diaza‐1,3‐dienes
Muhan Liang   +3 more
wiley   +1 more source

Trypanocidal Effects of Polyprenylated Benzophenone Enriched Brazilian Red Propolis Extract and Its Isolated Constituent. [PDF]

open access: yesChem Biodivers
Oliveira ND   +9 more
europepmc   +1 more source

Transplacental transfer efficiency of environmental chemicals in association with gestational diabetes mellitus. [PDF]

open access: yesEnviron Int
Leader J   +12 more
europepmc   +1 more source

Phosphoryl Radicals from Trivalent Iminyl Phosphines: A Photocatalytic Approach to N‐Phosphoryl Azetidines

open access: yesAngewandte Chemie, Volume 138, Issue 29, 13 July 2026.
Photochemically generated phosphoryl radicals from iminyl phosphines enable strain‐release addition to azabicyclobutanes, providing access to elusive N‐phosphoryl azetidines. Combined experimental, computational, and EPR studies reveal an unconventional water‐assisted photoredox pathway.
Chandu G. Krishnan   +4 more
wiley   +2 more sources

Dilithium Enediamide Derived From a 1,4‐Diaza‐1,3‐diene: Reactivity of a Strongly N‐Basic, Highly C‐Nucleophilic Compound Toward C–H Acids

open access: yesEuropean Journal of Inorganic Chemistry, Volume 29, Issue 20, 17 July 2026.
The lithium enediamide complex 2 with intrinsically inverted C–N bond polarity combines strong basicity with unusual reactivity: deprotonation of malonates enables C–C bond formation without electron transfer. Depending on malonate substitution, electrophilic substitution or addition occurs at the enediamide CC bond.
Muhan Liang   +3 more
wiley   +1 more source

Urinary levels of phenolic compounds in women working in beauty salons. [PDF]

open access: yesSci Rep
Moradi M   +6 more
europepmc   +1 more source

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