Results 91 to 100 of about 10,665 (213)

Heteroaryl‐Substituted Polyfluorobiaryls Synthesis via Palladium‐Catalyzed Double C─H Bond Functionalization Using Palladium 1,4‐Migration Associated to Direct Arylation

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 13, 13 April 2026.
Fluoro substituents on a benzene ring linked to a 2‐bromoaryl group enables the selective activation of one of its C─H bonds via Pd‐1,4‐migration. Then, Pd‐catalyzed direct coupling with heteroarenes produces C2’‐heteroarylated 1,1′‐biaryls. In this reaction, the new C–C bond arises from the functionalization of two C─H bonds.
Norman Le Floch   +2 more
wiley   +1 more source

Synthesis, spectroscopic and crystal structure analysis of 2-amino-5,5-dimethyl-7-oxo-4,5,6,7-tetrahydro-1-benzothiophene-3-carbonitrile and-3-carboxamide [PDF]

open access: yes, 2009
The preparation of 2-amino-5,5-dimethyl-7-oxo-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxamide via the intermediate 2-amino-5,5-dimethyl-7-oxo-4,5,6,7-tetrahydro-1-benzothiophene-3-carbonitrile is described, along with details of the crystal structure ...
Begum, N.S.   +4 more
core   +1 more source

Hypervalent Iodine‐Mediated Synthesis of Sulfones Using Organozinc Pivalates and Sulfinate Salts

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 13, 13 April 2026.
A general protocol for sulfone synthesis via sulfonyl‐containing hypervalent iodine reagents and organozinc pivalates is described. The method is practical, provides a broad scope of sulfone in moderate to high yield. bicyclo[1.1.1]pentane‐sulfones are also disclosed and a one‐pot synthesis of Diels–Alder adduct is presented. Sulfones are key motifs in
José C. Cunha   +4 more
wiley   +1 more source

Mononuclear piano-stool iron 2-ethynylbenzo[b]thiophene complex: crystal structure and reversible oxidation studied by spectro-electrochemical and DFT methods [PDF]

open access: yes, 2017
A mononuclear iron complex with 2-ethynylbenzo[b]thiophene C-coordinated to the (η5 -Cp*)(η2 -dppe)Fe ( Cp* = pentamethylcyclopentadienyl, dppe = 1,2-diphenylphosphinoethane) framework (1) was successfully prepared and characterized by 1H NMR ...
Hartl, František   +7 more
core   +1 more source

Functional Metal Complexes for Solar–Light‐Driven Energy Conversion

open access: yesAdvanced Materials, Volume 38, Issue 22, 17 April 2026.
This review provides an exhaustive summary of the recent advancements of functional metal complexes in solar‐to‐electrical, ‐chemical, and ‐thermal energy conversion, comprising material categories, design strategies, underlying principles of operation, and identified improvement of performances.
Yanyan Qin   +3 more
wiley   +1 more source

Crystal structure of ethyl 1′,1′′-dimethyl-2′′,3-dioxo-3H-dispiro[benzo[b]thiophene-2,3′-pyrrolidine-2′,3′′-indoline]-4′-carboxylate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title compound, C23H22N2O4S, the pyrrolidine ring has an envelope conformation with the spiro C atom, shared with the indoline ring system, as the flap. The mean planes of the benzothiophene and indoline ring systems are inclined to the mean plane
M. P. Savithri   +4 more
doaj   +1 more source

Insights in the antioxidant activity of diarylamines from the 2,3-dimethylbenzo[b]thiophene through the redox profile [PDF]

open access: yes, 2009
Cyclic voltammetry was used to evaluate the antioxidant activity of 7-aryl or 7-heteroarylamino-2,3-dimethylbenzo[b]thiophenes previously synthesized by some of us, comparing their oxidation potentials with those of the well-known synthetic standards ...
Abreu, Rui M.V.   +4 more
core   +1 more source

Substitutive Approach Toward Heteroaromatic Amino Alcohols Accessed Through Dioxolanyl Radical Linchpin

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 7, 1 April 2026.
A dioxolanyl linchpin has been used to synthesize aryl ethanolamines from readily available aryl bromide and amine starting materials using a metallaphotoredox/substitution telescoped sequence. This combinatorial approach allows for a wide synthetic scope of both heteroarenes and cyclic amines. Aryl ethanolamines are an important functional group found
Justin J. Chang   +4 more
wiley   +1 more source

Sonochemical Degradation of Benzothiophene (BT) in Deionized Water, Natural Water and Sea Water

open access: yesMolecules, 2019
This paper deals with the sonochemical water treatment of polycyclic aromatic sulfur hydrocarbons (PASHs), one of the most common impurities found in waste water coming from petroleum industry.
Khadijah M. Al-Zaydi   +4 more
doaj   +1 more source

Gate‐Dielectric Surface Engineering With Fluorinated Monolayers: Minimizing Contact Resistance and Nonidealities in OFETs

open access: yesAdvanced Electronic Materials, Volume 12, Issue 7, 6 April 2026.
Surface engineering of gate dielectrics with fluorinated self–assembled monolayers significantly improves the performance of organic field–effect transistors. In this study, Al2O3 functionalized with fluorinated phosphonic acids reduces contact resistance and hysteresis while achieving near‐zero threshold voltages, offering an alternative to ...
Shaghayegh Mesforush   +9 more
wiley   +1 more source

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