Results 161 to 170 of about 103,633 (342)

Continuous Flow Oxidation of Alcohols to Carboxylic Acids Using a Ternary Pd/C‐Pt/C‐Ru/C Catalyst and Molecular Oxygen. Application to the Synthesis of 2,5‐Frandicarboxylic Acid

open access: yesChemistryEurope, EarlyView.
A ternary metal catalyst system based on Pd/C, Pt/C, and Ru/C is found to be highly effective and robust for oxidizing alcohols to carboxylic acids using molecular oxygen. Combining the catalytic oxidation system with continuous flow, the conversion of 5‐hydroxymethylfurfural (HMF) into 2,5‐furandicarboxylic acid (FDCA), a bioplastics precursor, is ...
Mamoru Hyodo   +5 more
wiley   +1 more source

NH‐Sulfilimine Synthesis Catalyzed by Nonheme Iron(II) Complex

open access: yesChemistryEurope, EarlyView.
Sulfilimines are emerging as valuable functional group in modern medicinal chemistry. Yet, their catalytic preparation is underexplored compared to sulfoximines. Here, the iron‐catalyzed synthesis of 14 examples of unprotected sulfilimines in good yields, under aerobic atmosphere and at room temperature, is described.
Léa Tesson   +2 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview

open access: yesChemistry – A European Journal, EarlyView.
The graphical abstract summarizes the review “Pd(II)‐Catalyzed Strategies for the β‐Arylation of α‐Amino Acids: An Overview”, highlighting representative Pd(II)‐catalyzed methods for the β‐arylation of α‐amino acids. Key mechanistic features, substrate diversity, and synthetic relevance of these transformations are showcased. Abstract Metal‐catalyzed C─
Davide Illuminati   +4 more
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Using the Colloidal Method to Prepare Au Catalysts for the Alkylation of Aniline by Benzyl Alcohol. [PDF]

open access: yesInt J Mol Sci, 2023
Hare LV   +5 more
europepmc   +1 more source

Solar-Driven Selective Benzyl Alcohol Oxidation in Pickering Emulsion Stabilized by CNTs/GCN Hybrids Photocatalyst [PDF]

open access: gold
Yunyi Han   +7 more
openalex   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome   +6 more
wiley   +1 more source

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