Results 1 to 10 of about 18,190 (164)

Selective Catalytic Oxidation of Benzyl Alcohol to Benzaldehyde by Nitrates [PDF]

open access: yesFrontiers in Chemistry, 2020
In this paper, ferric nitrate was used to oxidize benzyl alcohol in a mild condition and demonstrated its better performance compared to HNO3. In the reaction, the conversion rate and product selectivity could be both as high as 95% in N2 atmosphere ...
Shurui Xu   +10 more
doaj   +3 more sources

Benzyl alcohol oxidation with Pd-Zn/TiO2: computational and experimental studies [PDF]

open access: yesScience and Technology of Advanced Materials, 2019
Pd–Zn/TiO2 catalysts containing 1 wt% total metal loading, but with different Pd to Zn ratios, were prepared using a modified impregnation method and tested in the solvent-free aerobic oxidation of benzyl alcohol.
Ewa Nowicka   +7 more
doaj   +2 more sources

Thermal control of the defunctionalization of supported Au25(glutathione)18 catalysts for benzyl alcohol oxidation [PDF]

open access: yesBeilstein Journal of Nanotechnology, 2019
Au25(SG)18 (SG – glutathione) clusters deposited on ZrO2 nanoparticles have been used as a catalyst for benzyl alcohol oxidation. Calcination was performed at different temperatures to study the ligand and particle size effect on the catalytic activity ...
Zahraa Shahin   +5 more
doaj   +2 more sources

Dynamically Cyclic Fe2+/Fe3+ Active Sites as Electron and Proton-Feeding Centers Boosting CO2 Photoreduction Powered by Benzyl Alcohol Oxidation [PDF]

open access: yesResearch
Solar-driven CO2 photoreduction holds promise for sustainable fuel and chemical productions, but the complex proton-coupled multi-electron transfer processes and sluggish oxidation half-reaction kinetics substantially hinder its efficiency.
Ben Lei   +8 more
doaj   +2 more sources

Toluene-2-monooxygenase expression and trichloroethene oxidizing activity of Burkholderia vietnamiensis G4 grown on benzyl alcohol and benzyl esters [PDF]

open access: yesApplied Microbiology and Biotechnology
Benzyl alcohol (BA) and two BA esters were examined for their ability to support growth of Burkholderia vietnamiensis G4 and expression of toluene-2-monooxygenase (T2MO) activity.
Alyssa M. Saito   +3 more
doaj   +2 more sources

Selective oxidation of benzyl alcohol to benzaldehyde over CoFe2O4 nanocatalyst

open access: yesCatalysis Communications, 2023
Co/Fe bimetallic spherical nanomaterials were synthesized by hydrothermal method as an efficient heterogeneous catalyst, which can catalyze the selective oxidation of benzyl alcohol to benzaldehyde by O2, thereby replacing stoichiometric oxidation ...
Guangdong Gao   +8 more
doaj   +1 more source

Efficient oxidation of benzyl alcohol on copper phyllosilicate catalysts

open access: yesJournal of Science: Advanced Materials and Devices, 2023
Two copper phyllosilicates were prepared via co-precipitation accompanied by hydrothermal treatment at pH constant. The obtained materials were physically characterized by XRD, H2-TPR, TEM, BET and XPS techniques.
Dang Thanh Trong   +5 more
doaj   +1 more source

Synthesis of Benzylic Alcohols by C–H Oxidation [PDF]

open access: yesJournal of the American Chemical Society, 2019
Selective methylene C-H oxidation for the synthesis of alcohols with a broad scope and functional group tolerance is challenging due to the high proclivity for further oxidation of alcohols to ketones. Here, we report the selective synthesis of benzylic alcohols employing bis(methanesulfonyl) peroxide as an oxidant.
Lalita Tanwar   +2 more
openaire   +3 more sources

Oxidant-Free Electrochemical Direct Oxidative Benzyl Alcohols to Benzyl Aldehydes Using Three-Dimensional Printing PPAR Polyoxometalate

open access: yesMolecules, 2023
The oxidation of benzyl alcohols is an important reaction in organic synthesis. Traditional methods for benzyl alcohol oxidation have not been widely utilized due to the use of significant amounts of precious metals and environmentally unfriendly ...
Wenhui Zhang   +9 more
doaj   +1 more source

Alcohols electrooxidation coupled with H2 production at high current densities promoted by a cooperative catalyst

open access: yesNature Communications, 2022
Electrochemical alcohol oxidation offers a promising approach to produce valuable chemicals that can be paired with fuel-producing reactions. Here, authors utilize gold and cobalt oxyhydroxide nanomaterials to obtain industrially-relevant electrolyzer ...
Zhenhua Li   +10 more
doaj   +1 more source

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