Results 201 to 210 of about 50,271 (281)

Increased calcification by erythrophagocytosis in aortic valvular interstitial cells

open access: yesESC Heart Failure, Volume 12, Issue 2, Page 1469-1473, April 2025.
Abstract Background Calcific aortic valve disease (CAVD) progresses over time to severe aortic stenosis and eventually heart failure. Recent evidence indicates that intraleaflet haemorrhage (ILH) strongly promotes CAVD progression. However, it remains poorly understood how it mechanistically contributes to valvular calcification.
Zihan Qin   +3 more
wiley   +1 more source

Mechanistic and Reactivity Insights into Diboron‐Mediated NN and NN Bond Scission

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights the emerging ability of diboron reagents to cleave both π‐bonded (N=N) and σ‐bonded (N—N) nitrogen–nitrogen linkages, integrating mechanistic understanding with recent synthetic applications. Diboron reagents have emerged as versatile reducing agents capable of transforming a broad range of functional groups through pathways like
Raúl Valderrama‐Callejón   +2 more
wiley   +1 more source

Iminodirhodium‐ and Iminocopper‐Catalyzed CH Activation: Chemoselective Oxidation of Alcohols and Aldehydes via Intermolecular Hydride Abstraction

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu   +2 more
wiley   +1 more source

From Gel to Crystal: Mechanism of HfO2 and ZrO2 Nanocrystal Synthesis in Benzyl Alcohol. [PDF]

open access: yesJ Am Chem Soc
Goossens E   +7 more
europepmc   +1 more source

Enantiospecific Acid‐Catalysed Hydroperoxidation of Scalemic Tertiary Benzylic Alcohols Facilitating a Concise Asymmetric Synthesis of Yingzhaosu C

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh   +2 more
wiley   +1 more source

Benzylation of Benzyl Alcohol on Layered Double Hydroxides.

open access: yesNIPPON KAGAKU KAISHI, 2001
Hiroshi SHIMADA, Takashi SASANOMA
openaire   +2 more sources

Electrochemical Three‐Component Synthesis of Heteroaryl Sulfonates

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
An electrochemical, metal‐free three‐component strategy for direct C(sp2)─H sulfonation of electron‐rich heteroarenes using SO2 and alcohols is described. Utilizing inexpensive graphite electrodes and practical SO2 stock solutions under mild conditions, this method provides straightforward access to heteroaryl sulfonates from simple building blocks ...
Po‐Chung Chien   +2 more
wiley   +1 more source

Monitoring and Mitigation Strategies for Hazardous Compounds in Chinese Rice Wine (Huangjiu): A Comprehensive Review

open access: yesFood Safety and Health, EarlyView.
This review elucidates the formation pathways and detection technologies for ethyl carbamate, biogenic amines, and higher alcohols in Huangjiu. It concludes that integrated control frameworks are essential to decouple safety risks from the metabolic processes responsible for flavor development.
Lulu Liu   +5 more
wiley   +1 more source

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