Formation of Bicyclic Skeletons by Aerobic, Manganese‐Mediated Cyclization of β‐Oxoesters
Manganese(III) promotes aerobic radical cyclization reactions of β‐oxoesters with an ω‐alkenyl side chain at the β’‐position to give bicyclic products with a 1,4‐dicarbonyl structure. Bicyclic perhydro‐pentalene, ‐indene, and ‐azulene, as well as decaline skeletons were accessed by aerobic manganese(III)‐mediated radical cyclizations of cyclic β ...
Julian Friedrich +2 more
wiley +1 more source
The effects of competition on exercise intensity and the user experience of exercise, during virtual reality bicycling for healthy adults across the lifespan. [PDF]
Palmieri JL, Deutsch JE.
europepmc +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
The mediating role of depression on the association between physical activity and cognitive function among older adults. [PDF]
Zhang H, Tian W, Qi G, Wei X.
europepmc +1 more source
The Cyano‐Diels–Alder Reaction: From Nitrile Activation to Functional Molecular Architectures
This Concept Article presents the evolution of the cyano‐Diels–Alder reaction from its early examples to its current development as a valuable synthetic tool for the preparation of N‐heterocycles, fused polycycles and functional chromophores, tracing the key breakthroughs that have transformed this underexplored transformation into a relevant platform ...
Giovanni Bottari
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Associations Between Perceived Neighbourhood Built Environment and the Maintenance of Regular Walking: A Role of Gender and Socioeconomic Status in a Cross-Sectional Study. [PDF]
Noh S, Choo J, Park S, Jae SY.
europepmc +1 more source
An efficient and straightforward methodology for the stereoselective and diastereospecific aminosilylation and hydrosilylation of heterobicyclic norbornene derivatives is introduced. The mild conditions enable the functionalization of norbornene substrates with broad functional‐group tolerance.
Daniel Kamzol +3 more
wiley +1 more source
Outdoor bicycle training following stroke: protocol development, feasibility testing and application guidelines. [PDF]
Villeneuve M +3 more
europepmc +1 more source
Mechatronic Bicycle Storage : Rotary bicycle storage developed for bicycle rooms
This bachelor thesis is aimed at creating an improved version of traditional two-story bicycle racks, common in bicycle rooms. The purpose is to remove the need for heavy lifting when loading and unloading bicycles, while simultaneously enhancing safety and utilization. The solution presented in this project is to create an automated rotary system that
Andrén Jakobsson, Martin +1 more
openaire +1 more source
Creativity and its link to epilepsy
Abstract Creative thinking represents one of our highest‐order cognitive processes, involving multiple cortical structures and an intricate interplay between several cortical and subcortical networks. It results in novel ideas that translate to useful products or concepts. The evolutionary purpose of creativity is therefore apparent, as it advances our
Itay Tokatly Latzer, Phillip L. Pearl
wiley +1 more source

