Results 41 to 50 of about 15,640 (302)
Catalytic Functionalization of Unactivated π‐Bonds Enabled by Bidentate Directing Auxiliaries
Angewandte Chemie, EarlyView.This review explores how bidentate directing auxiliaries have advanced transition‐metal catalysis for unactivated alkene/alkyne functionalization. By leveraging chelated intermediates, bidentate directing auxiliaries enable precise hydrofunctionalization, difunctionalization, and C─H activation of π‐bonds with unique selectivity and reactivity.
Seunghyeon Cho +4 more
wiley +2 more sources
Nonlocomotory Robotic Strategies for Dynamic Rotation Control in Terrestrial Robots: A Review
Advanced Robotics Research, EarlyView.Terrestrial robots increasingly require rapid body rotation to maintain stability and agility in complex environments. This review shows nonlocomotory rotational control strategies that operate without ground contact, including reaction wheels, tails, bars, limbs, and thrusters.
Y. Liang +14 more
wiley +1 more source
Ultra‐Thin and Highly Insulating Aromatic Monolayers by N‐Heterocyclic Carbenes
Angewandte Chemie, EarlyView.By using N‐heterocyclic carbenes extremally insulating and at the same time as thin as 0.3 nm molecular films are formed. The charge transport calculations indicate absence of destructive quantum interference effect which was so far the only way to suppress conductivity in aromatic molecules.
Mateusz Wróbel +6 more
wiley +2 more sources
JTLU special issue editorial: Bicycling in changing urban regions
Journal of Transport and Land Use, 2018 As communities around the globe contemplate the future of their transport portfolio, bicycling's role has increasingly cropped up as a key discussion point. Up until a few years ago, bicycling's value was largely fueled by a loyal advocacy base.
Kevin J. Krizek +2 more
doaj +1 more source
Frontiers in Psychology, 2023 Mountain biking (MTB) is a challenging activity where riders face constant decisions on whether to attempt technical paths or features (e.g., wooden ramps and jumps) that pose risk for falls and injuries. Risk homeostasis theory posits that riders pursue
Emily P. Chilton, Stephen N. Robinovitch
doaj +1 more source
A Perspective on the Applications of Triphasic Gas Storage in Electrochemical Systems
Advanced Science, EarlyView.Gas storage in microporous materials positioned locally at an electrode or electrocatalyst surface enhances electrochemical processes. Abstract Microporous materials store gases under dry conditions (e.g., hydrogen or oxygen via physisorption), but in some cases microporous materials also show triphasic (e.g., in a solid|gas|liquid system) gas storage ...
Zhongkai Li +9 more
wiley +1 more source
Direct δ‐Lactone Synthesis From Free Alcohols via Photoinduced δ‐C(sp3)–H Carbonylation in Flow
Angewandte Chemie, EarlyView.Herein, we have developed a photo‐flow platform for the δ‐C(sp3)─H carbonylative lactonization of free alcohols with carbon monoxide. The transformation integrates alkoxyl radical generation, selective 1,5‐HAT, CO incorporation, and radical–polar crossover to enable direct access to δ‐lactones from simple alcohol precursors.
Prakash Chandra Tiwari +2 more
wiley +2 more sources
Advanced Science, EarlyView.A one‐step, asymmetric reductive coupling of alkynes and oxa‐ and aza‐bicyclic olefins using a cobalt/photoredox catalytic system through desymmetrization. ABSTRACT Bicyclo[2.2.1]heptane frameworks represent a privileged structural motif prevalent in numerous natural products and bioactive molecules.
Subhankar Pradhan +5 more
wiley +1 more source
Journal of Cycling and Micromobility ResearchAccurate bicycling volume estimation is crucial for making informed decisions and planning about future investments in bicycling infrastructure. However, traditional link-level volume estimation models are effective for motorized traffic but face ...
Mohit Gupta +4 more
doaj +1 more source